61592-66-3Relevant academic research and scientific papers
Correction to: Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H (Organic Letters (2016) 18: 15 (3886-3889) DOI: 10.1021/acs.orglett.6b
-
, p. 5186 - 5187 (2016/10/18)
The wrong enantiomers of (?)-gabosine H (5), (?)-epigabosine H (epi-5) and intermediates 6?10, 11a,b, and 12?22 were drawn in the Abstract, Table of Contents, and Schemes 2?6. The correct structural drawings for these compounds are provided. The corrected
Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H
Vulovic, Bojan,Kolarski, Dusan,Bihelovic, Filip,Matovic, Radomir,Gruden, Maja,Saicic, Radomir N.
supporting information, p. 3886 - 3889 (2016/08/16)
1,6-Diynes with a t-butylcarbonate group in the propargylic position undergo gold(I)-catalyzed domino-cyclization which affords α-hydroxycyclohexenones. The described sequence can be applied on functionalized, highly oxygenated substrates, as examplified
Cleavage of Unsaturated α-Ketols to ω-Oxo-α,β-unsaturated Acids
Floresca, Rey,Kurihara, Masaaki,Watt, David S.,Demir, Ayhan
, p. 2196 - 2200 (2007/10/02)
Sodium periodate is a better reagent than sodium bismutate, manganese dioxide, or lead tetraacetate for the cleavage of unsaturated α-ketols and affords ω-oxo-α,β-unsaturated acids in good yield.The combination of this cleavage reaction and a rhodium(I)-m
Hypervalent Iodine Oxidation of α,β-Unsaturated Carbonyl Compounds
Tamura, Yasumitsu,Yakura, Takayuki,Terashi, Hiroaki,Haruta, Jun-Ichi,Kita, Yasuyuki
, p. 570 - 577 (2007/10/02)
Oxidation of non-enolizable α,β-unsaturated carbonyl compounds and enolizable β-monosubstituted α,β-unsaturated carbonyl compounds with phenyl iodine(III) diacetate (PIDA) in methanolic potassium hydroxide gave α-hydroxydimethylacetal β-methoxy products,
