61594-83-0Relevant academic research and scientific papers
Regiospecific oxidation of an alkyl group of aromatic amine to carbonyl group by DDQ in aq. medium
Mane, Madhav S.,Balaskar, Ravi S.,Gavade, Sandip N.,Pabrekar, Pramod N.,Shingare, Murlidhar S.,Mane, Dhananjay V.
experimental part, p. 1039 - 1042 (2012/06/01)
The regiospecific oxidation of alkyl group of both sterically hindered and unhindered aromatic amine to corresponding carbonyl compound was done in aq. medium by using DDQ. The optimized reaction protocol was found to be most simple, high yielding and novel method for oxidation of alkyl group of aromatic amine in to its carbonyl compound.
Simple Synthetic Route to 4-Aminobenzaldehydes from Anilines
Liedholm, Brita
, p. 2235 - 2242 (2007/10/02)
Anilines unsubstituted at the 4-position react under mild conditions in Me2SO-HCl solvent (H+ = 0.6 mol dm-3) to give substituted 4-aminobenzaldehydes in high yields; although addition of CuCl2 gives a cleaner product, it is not esse
REGIOSPECIFIC OXIDATION BY DDQ OF UNHINDERED ALKYL GROUPS IN STERICALLY HINDERED AROMATIC AMINES
Lal, Bansi,Gidwani, Ramesh M.,Reden, Jurgen,Souza, Noel J. de
, p. 2901 - 2904 (2007/10/02)
DDQ oxidises an unhindered activated alkyl group to a carbonyl or a hydroxymethyl group depending on the nature of the substitution, in a sterically hindered aromatic amine.
