61608-90-0Relevant academic research and scientific papers
Amide-Directed C?H Sodiation by a Sodium Hydride/Iodide Composite
Huang, Yinhua,Chan, Guo Hao,Chiba, Shunsuke
supporting information, p. 6544 - 6547 (2017/05/29)
A new protocol for amide-directed ortho and lateral C?H sodiation is enabled by sodium hydride (NaH) in the presence of either sodium iodide (NaI) or lithium iodide (LiI). The transient organosodium intermediates could be transformed into functionalized aromatic compounds.
Aldimine-directed branched-selective hydroarylation of styrenes
Lee, Pin-Sheng,Yoshikai, Naohiko
supporting information, p. 1240 - 1244 (2013/03/13)
Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal. Copyright
