616215-37-3Relevant academic research and scientific papers
Nitrogen inversion as a diastereomeric relay in azasugar synthesis: The first synthesis of adenophorine
Maughan, Michael A. T.,Davies, Ieuan G.,Claridge, Timothy D. W.,Courtney, Steve,Hay, Phil,Davis, Benjamin G.
, p. 3788 - 3792 (2007/10/03)
A temperature-dependent relay of chirality is based on the inversion of the nitrogen lone pair in cyclic azasugars. Elimination from the conformation preferred at a given temperature leads to a cyclic imine, and in a subsequent nucleophilic attack the ste
