616241-13-5Relevant articles and documents
Asymmetric catalytic aza-Morita-Baylis-Hillman reaction using chiral bifunctional phosphine amides as catalysts
Qi, Ming-Juan,Ai, Teng,Shi, Min,Li, Guigen
, p. 1181 - 1186 (2008)
The asymmetric catalytic aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with α,β-unsaturated ketones has been successfully conducted by using chiral bifunctional phosphine amides as catalysts. A series of new chiral bifunctional phosphine amide
Asymmetric aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with activated olefins catalyzed by chiral phosphine Lewis bases bearing multiple phenol groups
Liu, Ying-Hao,Chen, Lian-Hui,Shi, Min
, p. 973 - 979 (2006)
In the aza-Morita-Baylis-Hillman reaction of N-sulfonated imines (N-arylmethylidene-4-methyl-benzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (EVK), and acrolein, we found that, through the use of catalytic amounts of chiral phosphi
Conformational lock in a Bronsted acid-Lewis base organocatalyst for the aza-Morita-Baylis-Hillman reaction
Matsui, Katsuya,Tanaka, Kouichi,Horii, Atsushi,Takizawa, Shinobu,Sasai, Hiroaki
, p. 578 - 583 (2006)
(S)-3-(N-Isopropyl-N-3-pyridinylaminomethyl)BINOL has been established as an efficient asymmetric bifunctional organocatalyst for the aza-MBH reaction. The acid-base functionalities cooperate in substrate activation and fixing of the organocatalyst confor
Chiral bifunctional organocatalysts bearing a 1,3-propanediamine unit for the aza-MBH reaction
Hirata, Shuichi,Tanaka, Kouichi,Matsui, Katsuya,Arteaga, Fernando Arteaga,Yoshida, Yasushi,Takizawa, Shinobu,Sasai, Hiroaki
, p. 1189 - 1192 (2013/10/22)
The introduction of a 1,3-propanediamine unit at the 3-position of (S)-BINOL using a methylene spacer led to the formation of a chiral bifunctional organocatalyst for the aza-Morita-Baylis-Hillman (aza-MBH) reaction. The organocatalyst 1k mediated aza-MBH
Cooperativity in the counterion catalysis of Morita/Baylis/Hillman reactions promoted by enantioselective trifunctional organocatalysts
Anstiss, Christopher,Liu, Fei
experimental part, p. 5486 - 5491 (2010/08/07)
New trifunctional organocatalysts with a NHTs Br?nsted acid were prepared and tested in their ability to promote the counterion catalysis of generic and aza-Morita/Baylis/Hillman reactions.The cooperativity between the counterion and the NHTs Br?nsted aci