617-00-5

Usage

InChI:InChI=1/C14H15N/c1-11-7-3-5-9-13(11)15-14-10-6-4-8-12(14)2/h3-10,15H,1-2H3

Upstream product

• 95-49-8 2-methylchlorobenzene 
• 95-46-5 2-methylphenyl bromide 
• 120-66-1 N-(2-methylphenyl)acetamide 
• 95-48-7 ortho-cresol 
• 636-21-5 o-toluidine hydrochloride 
• 95-53-4 o-toluidine 
• 142-04-1 aniline hydrochloride 
• 615-37-2 ortho-methylphenyl iodide 
• 19020-41-8 N-acetyl-2,2'-dimethyldiphenylamine 
• 57-13-6 urea 
• 599-75-7 2-methylphenyl tosylate 
• 2093-46-1 2-methylphenyl diazonium tetrafluoroborate 
• 108-41-8 1-chloro-3-methylbenzene 
• 7003-32-9 2-METHYLCYCLOHEXYLAMINE 

Downstream Products

• 22695-18-7 N,N-di-o-tolylthiourea 
• 19020-41-8 N-acetyl-2,2'-dimethyldiphenylamine 
• 49785-66-2 2-methyl-N-phenyl-N-(o-tolyl)aniline 
• 566148-75-2 3-methoxy-N,N-bis(2-methylphenyl)aniline 
• 1184924-16-0 3-methyl-N,N-bis(2-methylphenyl)aniline 
• 1184924-15-9 4-methyl-N,N-bis(2-methylphenyl)aniline 
• 7287-73-2 2,2',2''-Trimethyltriphenylamine 
• 1247868-15-0 3,5-dimethyl-N,N-bis(2-methylphenyl)aniline 
• 1247868-16-1 2,6-dimethyl-N,N-bis(2-methylphenyl)aniline 
• 1629189-68-9 C₂₁H₂₁N 
• 49785-51-5 2-(di-o-tolylamino)benzoic acid 
• 49785-50-4 N_.N-Di-o-tolylanthranilsaeuremethylester 

Relevant academic research and scientific papers

Highly efficient chrysene emitters based on optimized side groups for deep blue emission

Diphenylamine substituted with methyl groups was used as a side group to realize high efficiency chrysene deep blue emitters. Three chrysene derivatives substituted with side groups were successfully synthesized: tetra-o-tolylchrysene-6,12-diamine (o-DPAC

Beyond the Hammett Effect: Using Strain to Alter the Landscape of Electrochemical Potentials

The substitution of sterically bulky groups at precise locations along the periphery of fused-ring aromatic systems is demonstrated to increase electrochemical oxidation potentials by preventing relaxation events in the oxidized state. Phenothiazines, whi

Synthesis of N-heterocyclic carbene-Pd(II)-5-phenyloxazole complexes and initial studies of their catalytic activity toward the Buchwald-Hartwig amination of aryl chlorides

Three new N-heterocyclic carbene (NHC)-Pd(II) complexes using 5-phenyloxazole as the ancillary ligand have been obtained in moderate to good yields by a one-pot reaction of the corresponding imidazolium salts, palladium chloride and 5-phenyloxazole under mild conditions. Initial studies showed that one of the complexes is an efficient catalyst for the Buchwald-Hartwig amination of aryl chlorides with various secondary and primary amines under the varied catalyst loading of 0.01-0.05 mol%, thus it will enrich the chemistry of NHCs and give an alternative catalyst for the coupling of challenging while cost-low aryl chlorides.

Method for synthesizing organic aromatic nitrogen-containing compound by taking nitrogen as nitrogen source

The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, and belongs to the field of organic synthesis. The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, which is characterized by comprising the following steps of: 1, reducing nitrogen by lithium powder to form lithium nitride; and 2, reacting the lithium nitride with a halogenated aromatic compound under the action of a transition metal catalyst, a ligand, alkali and a phase transfer catalyst to obtain an organic aromatic nitrogen-containing compound; wherein the two steps of reactions are completed in one pot. The method realizes the conversion of cheap nitrogen to the high-added-value aromatic nitrogen-containing compound, and also has the advantages of mild reaction conditions, good compatibility of substrate functional groups, high yield and the like.

One-pot synthesis of symmetrical and asymmetrical diphenylamines from guanidines with aryl iodide using Cu/Cu2O nanocatalyst

This work reports the selective one-pot synthesis of symmetrical and asymmetrical amines from guanidines as ammonia surrogate. The use of guanidine as ammonia source will eliminate the need of handling liquid ammonia. The reaction was performed using Cu/Cu2O nanocatalyst under ligand-free condition. The synthesized catalyst was characterized by a various technique like XRD, FEG-SEM, HRTEM and XPS. The different diphenylamines are produced in good to very good yields. Recyclability study of catalyst shows that up to five cycles there is no significant loss in its activity.

Direct Synthesis of Diphenylamines from Phenols and Ammonium Formate Catalyzed by Palladium

Arylamines are commercially and synthetically useful compounds with a wide variety of applications. Their preparation has been traditionally achieved using metal-catalyzed C?N coupling reactions with aryl halides. In this work, 17 different diarylamines are prepared from phenols by using ammonium formate as the aminating reagent. Phenolic compounds are more desirable feedstocks, owing to their availability from lignin, making them valuable biorenewable alternatives to aryl halides. Ammonium formate is found to be a convenient surrogate for ammonia and a useful aminating reagent for phenols. Diarylamine products are obtained in good to excellent yields while only water and CO2 are generated as byproducts of the transformation.

A green and mild procedure to selective synthesis of diarylamine via domino reaction of aryl halides and arginine catalyzed by magnetic-MOF

Efficient and selective direct synthesis of diarylamines from aryl halides and arginine as a nitrogen-donor reagent is reported. Arginine, which is an oral supplement, acts as a useful nitrogen source donor in the copper-catalyzed reaction. Fe3O4/Cu3(BTC)2, which was easily separated and recycled with a magnet, improved the rate and facilitation of the synthesis of diarylamines selectively. The introduction of a new and available N-source, simple magnetic separation process, normal atmospheric conditions, and excellent yields under mild reaction conditions are other important features of this work.

Intramolecular Charge Transfer Controls Switching Between Room Temperature Phosphorescence and Thermally Activated Delayed Fluorescence

Chemical modification of phenothiazine-benzophenone derivatives tunes the emission behavior from triplet states by selecting the geometry of the intramolecular charge transfer (ICT) state. A fundamental principle of planar ICT (PICT) and twisted ICT (TICT

1,9,10-SUBSTITUTED PHENATHIAZINE DERIVATIVES WITH STRAINED RADICAL CATIONS AND USE THEREOF

Compounds for use in a rechargeable battery are provided, including a compound according to the formula: wherein R1 and R9 are independently selected from the group consisting of H, alkyl, aryl, perfluoroaryl, perfluoroalkyl, alkylar

Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts

In the presence of supported Pd nanoparticle catalysts, e.g., Pd/Al2O3, various diphenylamines could be synthesized through acceptorless formal arylation using NH3 or its surrogates, e.g., urea, as nitrogen sources and cyclohexanones as arylation sources. The observed catalysis was truly heterogeneous, and the catalyst was reusable with retention of its high catalytic performance.