61820-00-6

Upstream product

• 35444-44-1 methyl adipoyl chloride 
• 3431-67-2 di-n-butylcadmium 
• 4144-60-9 6-oxodecanoic acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 693-03-8 n-butyl magnesium bromide 
• 87921-65-1 (2-Butyl-cyclopropoxy)-trimethyl-silane 
• 292638-85-8 acrylic acid methyl ester 
• 126203-40-5 6,6-Dimethoxy-decanoic acid methyl ester 
• 86014-56-4 Hexanedioic acid methyl ester pyridin-2-yl ester 
• 109-72-8 n-butyllithium 
• 109-65-9 1-bromo-butane 
• 627-91-8 adipic acid monomethyl ester 
• 124-04-9 Adipic acid 

Downstream Products

• 4144-60-9 6-oxodecanoic acid 
• 5579-78-2 ε-decalactone 
• 16899-10-8 6-hydroxydecanoic acid 

Relevant academic research and scientific papers

A Facile Method for the Cleavage of Acetals by the Combined Use of Samarium Trichloride and Chlorotrimethylsilane

Cleavage of acetals by a stoichiometric or a catalytic amount of samarium trichloride and chlorotrimethylsilane in the absence of a proton source proceeded smoothly giving the corresponding carbonyl compounds in high yields.

Experimental and Theoretical Studies on the Mechanism of 1,2-Migration of Vinyl and Formyl Substituents in Free Radicals

Vinyl and formyl groups undergo rearrangements of the type X=CH-CMe2-C*H2 -> C*Me2-CH2-CH=X (X = CH2 or O) with comparable rates (106 - 107 l/mol*s, 20 deg C).This result is in line with high-level ab initio calculations performed on the basic systems, i.e.X=CH-CH2-C*H2, which give barriers of activation of 14.9 (CH2=CH-CH2-C*H2) and 19.2 kcal/mol (O=CH-CH2-C*H2), respectively.The calculations suggest that the rearrangements proceed via cyclopropane-like intermediates.