61845-41-8

Upstream product

• 93-59-4 Perbenzoic acid 
• 4789-73-5 2-phenyl-6-methoxyquinoline 
• 19062-82-9 2-cyano-6-methoxyquinoline N-oxide 
• 5263-87-6 6-methoxy quinoline 
• 108-86-1 bromobenzene 
• 6563-13-9 6-methoxyquinoline N-oxide 
• 100-63-0 phenylhydrazine 
• 98-80-6 phenylboronic acid 
• 591-51-5 phenyllithium 

Downstream Products

• 50593-72-1 4-chloro-6-methoxy-2-phenylquinoline 
• 47627-53-2 N⁴,N⁴-diethyl-N¹-(6-methoxy-2-phenyl-[4]quinolyl)-1-methyl-butanediyldiamine 
• 4789-73-5 2-phenyl-6-methoxyquinoline 

Relevant academic research and scientific papers

Visible-light-promoted c2 selective arylation of quinoline and pyridine n-oxides with diaryliodonium tetrafluoroborate

A protocol of visible-light-promoted C2 selective arylation of quinoline and pyridine N-oxides, with diaryliodonium tetrafluoroborate as an arylation reagent, using eosin Y as a photocatalyst for the construction of N-heterobiaryls was presented. This met

Preparation method of 2- aryl substituted quinoline nitrogen oxide compound

The preparation method 2 - of, aryl-substituted quinoline nitrogen oxide is 2 - The method, according to the present invention provides,aryl-substituted quinoline nitrogen oxide compound, in a nitrogen atmosphere at room temperature, The method for prepar

KMnO4-mediated direct selective radical cross-coupling: An effective strategy for C2 arylation of quinoline N-oxide with arylboronic acids

Direct C[sbnd]H functionalization of quinoline N-oxides with arylboronic acids is achieved using KMnO4 as the sole and efficient oxidative system. This method provides an efficient protocol to construct regioselectively 2-arylquinoline N-oxides

KMnO4-mediated direct C2-selective C?H arylation of quinoline N-oxides with aromatic hydrazines

An efficient protocol for the synthesis of 2-arylquinoline N-oxides has been developed via KMnO4-mediated cross-coupling reaction of quinoline N-oxides with aromatic hydrazines in moderated to good yields. The reactions proceeded efficiently over a broad range of substrates with excellent regioselectivity and functional group tolerance.

One-pot synthesis and fluorescence properties of 2-arylquinolines

The one-pot synthesis of 2-arylquinoline with arylamines, arylaldehyde, and 1,1-diethoxyethane were studied using a catalytic amount ytterbium triflate. Various 2-arylquinolines showed fluorescence properties and the fluorescence was quenched by introduci

Quinoline Nitroxide Radicals. Ipso-Attack in the Reaction between 2-Methoxy and 2-Cyanoquinoline N-oxide, and Phenylmagnesium Bromide

2-Methoxy and 2-cyanoquinoline N-oxide, when treated with phenylmagnesium bromide, undergo a nucleophilic ipso-attack at C-2, yielding, by elimination of methoxymagnesium bromide or cyanomagnesium bromide, the corresponding 2-phenylquinoline N-oxides, which react with the excess of Grignard reagents forming 2,2-diphenylquinoline 1-oxyls.Even when the methoxy and cyano groups are in position 4, the attack by the Grignard reagent takes place at C-2 giving 2-phenylquinolines and 2-phenylquinoline N-oxides by elimination by hydroxymagnesium bromide and bromomagnesium hydride, respectively; the formation of 2,2-diphenylquinoline 1-oxyls in these reactions is discussed.