61854-11-3Relevant academic research and scientific papers
REACTIONS OF ARENESULFENYL CHLORIDES WITH METHYLENECYCLOALKANES AND VINYLCYCLOPROPANE
Magerramov, A. M.,Gyul'akhmedov, L. M.,Sadovaya, N. K.,Zhdankin, V. V.,Koz'min, A. S.
, p. 2014 - 2021 (2007/10/02)
The direction and the composition of the products in the addition of 2,4-dinitrobenzenesulfenyl chloride to methylenecyclopentane, methylenecyclobutane, and vinylcyclopropane and also of 2-nitrobenzenesulfenyl chloride to methylenespirohexane depend
DOPING-ADDITION OF ARENESULFENYL CHLORIDES TO OLEFINS IN THE PRESENCE OF PERCHLORIC ACID AND THE LITHIUM PERCHLORATE. CRITERIA OF LIMITING VARIANTS IN MECHANISM OF THESE REACTIONS
Kartashov, V. R.,Sorobogatova, E. V.,Grudzinskaya, E. Yu.,Zefirov, N. S.,Caple, R.
, p. 2231 - 2242 (2007/10/02)
The addition of perchloric acid in the addition reactions of sulfenyl chlorides to olefins gives rise to a doping effect, which exceeds the analogous effect of lithium perchlorate.Analysis of the dependence of rate of the model reactions and the yields of the doping products on the perchloric acid and lithium perchlorate concentrations showed that the doping additions can operate by two mechanisms, i.e., by the mechanism of a normal salt effect in the controlling state and by a mechanism of ion-pair exchange in the subsequent fast stages.
KINETICS AND DOPING EFFECT IN THE ADDITION OF 2,4-DINITROPHENYLSULFENYL CHLORIDE AND DITHIOCYANOGEN TO OLEFINS
Skorobogatova, E. V.,Grudzinskaya, E. Yu.,Afanas'ev, P. S,Kartashov, V. R.,Zefirov, N. S.,Caple, R.
, p. 1814 - 1822 (2007/10/02)
The rate of the doping addition in the reactions of 2,4-dinitrophenylsulfenyl chloride with cyclohexene an methylenecyclobutane and of dithiocyanogen with cyclohexene and substituted styrenes in the presence of lithium perchlorate is described by the normal salt effect equation.On the other hand, the rate of formation of the doping products may exceed or lag behind the increase in the total reaction rate.These results were interpreted in the framework of an ion-pair mechanism.
REACTION OF SULFENYL HALIDES WITH ALKENES IN THE PRESENCE OF PERCHLORIC ACID
Grudzinskaya, E. Yu.,Skorobogatova, E. V.
, p. 1710 - 1713 (2007/10/02)
In the reaction of 2,4-dinitrobenzenesulfenyl chloride and benzenesulfenyl chloride with cyclohexane, propene, and styrene in acetic acid in the presence of perchloric acid the corresponding solvent adducts are formed with yields of 47-75percent.The effect of the perchloric acid on the rate of the reaction of 2,4-dinitrobenzenesulfenyl chloride with cyclohexene is described by an equation for homogeneous catalysis.On the basis of the kinetic data two possible schemes are proposed for the effect of perchloric acid on the formation of the solvent adducts, i.e., a mechanism of homogeneous catalysis and by an ion-exchange mechanism in the noncontrolling stages of the reaction.
