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6192-13-8

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6192-13-8 Usage

Uses

Neodymium Acetate, mainly used for glass, crystal and capacitors. Colours glass delicate shades ranging from pure violet through wine-red and warm gray. Light transmitted through such glass shows unusually sharp absorption bands. It is useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens. It is highly valued in glass manufacturing for its attractive purple coloring to glass.

Chemical Properties

light purple crystal(s) [STR93]

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 6192-13-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,1,9 and 2 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 6192-13:
(6*6)+(5*1)+(4*9)+(3*2)+(2*1)+(1*3)=88
88 % 10 = 8
So 6192-13-8 is a valid CAS Registry Number.
InChI:InChI=1/3C2H4O2.Nd/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3

6192-13-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name neodymium(3+),triacetate,pentahydrate

1.2 Other means of identification

Product number -
Other names neodimium acetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6192-13-8 SDS

6192-13-8Relevant articles and documents

Anhydrous neodymium(III) acetate

Torres, Sonia Gomez,Meyer, Gerd

, p. 231 - 233 (2008)

Anhydrous neodymium(III) acetate, Nd(OAc)3 was obtained as light purple single crystals by direct oxidation of neodymium metal with malonic acid in a glass ampoule at 180 °C. It crystallizes with the monoclinic space group P21/a (no. 14) with a = 2201.7(2), b = 1850.0(1), c = 2419.0(3) pm, β = 96.127(8)°, V = 9796.8(1) · 106 · pm3, Z = 40 [Nd(OAc)3], R1 = 0.0430 [I 0 > 2σ(I0)]. Most of the Nd3+ cations are coordinated by nine (or eight) oxygen atoms of acetate ligands which bridge these polyhedra to slightly waved layers which are stacked in the [010] direction.

Energy Migration Up-conversion of Tb3+ in Yb3+ and Nd3+ Codoped Active-Core/Active-Shell Colloidal Nanoparticles

Prorok, Katarzyna,Pawlyta, Miros?awa,Strek, Wies?aw,Bednarkiewicz, Artur

, p. 2295 - 2300 (2016/05/10)

The intentional design of chemical architecture of lanthanide doped luminescent nanoparticles through the proper selection of dopants in core-shell and core-shell-shell structures enables optimization of their optical properties. Such an approach allows one to achieve energy transfer up-conversion (ETU) and energy migration mediated up-conversion (EMU) and green emission from Tb3+ ions with the Yb3+ and Nd3+ sensitizers at 980 and 808 nm photoexcitation, respectively. The [Nd3+ → Yb3+]→ [Yb3+ → Tb3+] EMU phenomenon was significantly enhanced by spatial displacement of the sensitizing Nd3+ ions from the activator Tb3+ ions by intentionally introducing an intermediate Yb3+ sensitizer layer forming a [Nd3+ → Yb3+] → [Yb3+] → [Yb3+ → Tb3+] system. Otherwise Tb3+ emission was considerably quenched by Nd3+ ions even though they were spitted between the core and shell, respectively. Moreover, (Tb3+,Yb3+) → (Tb4+,Yb2+) valence change has been discovered to limit the Tb3+ up-conversion emission. The studies explain how the chemical architecture of the smartly designed active-core @ active-shell luminescent nanoparticles may improve their spectral properties.

Syntheses, structures and photophysical properties of heterotrinuclear Zn2Ln clusters (Ln = Nd, Eu, Tb, Er, Yb)

Xu, Hai-Bing,Zhong, Ye-Teng,Zhang, Wei-Xiong,Chen, Zhong-Ning,Chen, Xiao-Ming

, p. 5676 - 5682 (2010/09/17)

Heterotrinuclear Zn2Ln (Ln = Nd 2, Eu 3, Tb 4, Er 5, Yb 6) clusters [(Znq2)2](μ-CH3COO){Ln(hfac) 2} (q = 8-hydroxylquinolinate, hfac = hexafluoroacetylacetonate) have been synthesized. The Zn2Ln framework is ligated by two q ligands featuring μ-phenoxo and two q ligands featuring μ3-phenoxo coordination modes, and one μ-CH3COO- anions. Since the short intramolecular separations of Zn...Ln (ca. 3.354-3.373 A) allow energy transfer from Znq2-based sensitizers to the Ln III centres through two energy transfer pathways, the lanthanide luminescence is indeed lighted up by excitation of the Znq 2-based chromopores. Photophysical measurements revealed that these Zn2Ln complexes exhibit the so-called dual emission originating from both Znq2-based luminophores and lanthanide emitters. By virtue of the dual luminescence with complementary colours, the Znq2-based cyan emission and EuIII-centred red luminescence are combined to generate a white-light emission in the Zn 2Eu (3) complex.

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