619319-91-4

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 53847-33-9 4-bromo-N-(diphenylmethylidene)aniline 
• 119-61-9 benzophenone 
• 17889-23-5 4-(trimethylsilyl)aniline 
• 17865-11-1 (4-(trimethylsilyl)phenyl)boronic acid 
• 106-40-1 4-bromo-aniline 

Downstream Products

• 619319-94-7 N-diphenylmethyl-4-trimethylsilyl aniline 
• 206656-23-7 N-(diphenylmethylene)-N'-(tert-butoxycarbonyl)-N'-[4-(N-tert-butoxycarbonylanilino)phenyl]-p-phenylenediamine 
• 206656-24-8 {4-[(4-Amino-phenyl)-tert-butoxycarbonyl-amino]-phenyl}-phenyl-carbamic acid tert-butyl ester 
• 200395-36-4 [4-(Benzhydrylidene-amino)-phenyl]-(4-trimethylsilanyl-phenyl)-carbamic acid tert-butyl ester 
• 200395-28-4 N-(diphenylmethylene)-N'-(tert-butoxycarbonyl)-N'-(4-bromophenyl)-p-phenylenediamine 
• 1026043-75-3 N-Benzhydrylidene-N'-(4-trimethylsilanyl-phenyl)-benzene-1,4-diamine 
• 200395-38-6 (4-Amino-phenyl)-(4-trimethylsilanyl-phenyl)-carbamic acid tert-butyl ester 
• 619319-80-1 N-diphenylmethyl-4-(trimethylsilyl)chloroacetanilide 
• 17889-23-5 4-(trimethylsilyl)aniline 

Relevant academic research and scientific papers

Copper-Catalysed Electrophilic Amination of Aryl(alkenyl) Boronic Acids with Nitrogen-Containing Hypervalent Iodine (III) Reagent

A copper-catalysed electrophilic N-imination of aryl(alkenyl) boronic acids with a stable hypervalent iodine(III) reagent containing a transferable (diarylmethylene)amino group is developed. The electrophilic C?N cross-coupling reaction proceeds smoothly at room temperature under oxidant-free and base-free conditions, which is further characterized by the broad functional group compatibility, thereof, extending the N-electrophile scope of electrophilic C?N cross-coupling outside the limitation of N?O and N?Cl reagents. (Figure presented.).

Synthesis of substituted oxindoles from α-chloroacetanilides via palladium-catalyzed C - H functionalization

A novel method for the synthesis of oxindoles is described. In the presence of catalytic palladium acetate and 2-(di-tert-butylphosphino)biphenyl, α-chloroacetanilides are converted to oxindoles in good to excellent yields with high functional group compatibility using triethylamine as a stoichiometric base. The cyclization is highly regioselective, obviating the need for prefunctionalized arenes. Plausible mechanistic pathways for the reaction are discussed. Copyright

Palladium-catalysed synthesis of monodisperse, controlled-length, and functionalized oligoanilines

The palladium-catalyzed animation of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis of two routes to oligoaniline precursors. One method consists of a bidirectional chain growth from a symmetric core piece, wherea