61945-92-4

Upstream product

• 1023-95-6 N,N-bis(trimethylsilyl)benzenesulfonamide 
• 107886-86-2 C₆H₁₈N₂SeSi₂ 
• 98-09-9 benzenesulfonyl chloride 
• 83215-02-5 difluoro-N-phenylsulfonylselenimide 

Downstream Products

• 108223-47-8 N-[2-Benzenesulfonyl-4,5-dimethyl-3,6-dihydro-2H-1λ⁴-[1,2]selenazin-(1E)-ylidene]-benzenesulfonamide 
• 108223-55-8 1-(phenylsulfonylamino)-9-(phenylsulfonylimino)-9-selenoperhydrofluorene 
• 108223-46-7 N-[2-Benzenesulfonyl-5-methyl-3,6-dihydro-2H-1λ⁴-[1,2]selenazin-(1E)-ylidene]-benzenesulfonamide 
• 60095-86-5 phenylsulfonylazo(p-diethylamino)benzene 
• 13909-34-7 N-benzylidenephenylsulfonamide 
• 19871-30-8 S,S-dimethyl-N-(phenylsulfonyl)sulfimide 
• 36176-88-2 N-(phenylsulfonyl)-p-bromobenzaldehyde imine 
• 108223-45-6 1,2-bis(phenylsulfonylamino)-3-cyclohexene 
• 1056-25-3 P,P,P-triphenyl-N-phenylsulfonylphosphine imide 
• 20445-53-8 Benzolsulfonsaeureamid, Verbindung mit Triphenylphosphinoxid 
• 3878-44-2 Triphenylphosphine selenide 
• 3147-03-3 N,N-diphenyl-N'-phenylsulfonylformamidine 
• 13707-43-2 N,N-dimethyl-N′-(phenylsulfonyl)formimidamide 
• 36176-89-3 N-(p-nitrobenzylidene)benzenesulfonamide 

Relevant academic research and scientific papers

Advances in Perhalogeno Thiocarbonyl, Selenocarbonyl and Selenodiimine Chemistry

Trifluoromethylselenylthiocarbonyls form with CF33-nClnSCl or CF3SeCl the corresponding disulfanes or selanesulfanes.Oxidation of CF3SeC(S)X, X = CF3Se, CF3S, Cl, or Br, with 3-Cl-C6H4C(O)OOH yields compounds CF3Se(X)C=S=O.Only decomposition products are obtained from (CF3Se)2CSe and Cl2, CF3SeCl, CF3SCl, or 3-Cl-C6H4C(O)OOH.The preparation of compounds RN=Se=NR, R = (CH3)3Si, CF3C(O), or CF3SO2, is described.Physical and spectroscopical data of the new substances are provided. - Keywords: Synthesis, Thiocarbonyl, Selenocarbonyl, Selenodiimine

N,N'-DIACYLSELENIUM DIIMIDES III. NEW METHODS OF SYNTHESIS

In the reaction of selenyl fluoride or chloride with N,N-bis(trimethylsilyl)sulfonamides N,N'-diacylselenium diimides (RSO2N=)2Se were obtained.Selenium diimides are also formed in the reaction of difluoroselenimides RSO2N=SeF2 with hexamethyldisiloxane.The difluoroselenimides were obtained by the reactions of selenium tetrafluoride with disilylated amides in a molar ratio of 1:1.