25201-44-9

Upstream product

• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 
• 100-52-7 benzaldehyde 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 22032-77-5 (E)-crotylmagnesium chloride 
• 4784-77-4 (E/Z)-crotyl bromide 
• 5908-41-8 benzoyltrimethylsilane 
• 1171-49-9 benzoyl-triphenyl-silane 
• 123290-13-1 phenyltriisopropylsilylmethanone 
• 36219-40-6 1-bromo-2-hydroxy-2-methyl-3-butene 
• 50599-02-5 2-methyl-1-phenyl-3-buten-1-one 
• 30295-79-5 (CH₃CH₂CH₂CH₂)3SnOCH(C₆H₅)CH(CH₃)CHCH₂ 
• 504-61-0 (E)-but-2-enol 
• 563-52-0 2-chloro-3-butene 
• 38169-04-9 (E)-crotyl iodide 

Downstream Products

• 122293-84-9 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2R)-2-methyl-1-phenyl-but-3-enyl ester 
• 122293-84-9 (1S,2S)-2-methyl-1-phenyl-3-buten-1-yl (R)-α-methoxy-α-(trifluoromethyl)phenylacetate 
• 105251-34-1 (3S*,4S*)-4-amino-3-methyl-4-phenyl-1-butene 
• 105251-35-2 (3R*,4S*)-4-amino-3-methyl-4-phenyl-1-butene 
• 75851-76-2 (Z)-1-phenyl-3-penten-1-ol 
• 75851-77-3 (E)-1-phenyl-3-penten-1-ol 
• 169827-08-1 (S,Z)-1-phenylhept-5-en-3-ol 
• 169827-07-0 (E)-1-phenyl-hept-5-en-3-ol 
• 28489-52-3 2,6-diphenyl-3-methylpyridine 
• 134370-17-5 5-(2-Oxo-1-methyl-2-phenylethyl)-3-phenyl-2-isoxazoline 
• 20047-50-1 (E)-2-methyl-1-phenyl-2-buten-1-one 
• 20047-49-8 (Z)-2-methyl-1-phenyl-2-buten-1-one 
• 1264758-34-0 ethyl 4-(2,5-dimethyl-6-phenylpyridin-3-yl)benzoate 
• 1264758-32-8 2,5-dimethyl-6-phenyl-3-p-tolylpyridine 

Relevant academic research and scientific papers

Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their insitu site-, diastereo-, and enantioselective additions to aldehydes and ketones

Sustainable, efficient, selective: A three-component, single-vessel Cu-catalyzed method for chemo-, diastereo-, and enantioselective conversion of B2(pin)2, monosubstituted allenes, and aldehydes or ketones to 2-B(pin)-substituted homoallylic alkoxides is described. Subsequent functionalization delivers valuable products in up to >98:2 d.r. and 97:3 e.r. (see scheme). Copyright

First catalytic allyltitanation reactions

Catalytic allyltitanation reactions were accomplished from dienes and aldehydes with only 5% of titanocene complexes at the expense of employing stoichiometric amounts of PMHS. The Royal Society of Chemistry 2005.

Formation and direct detection of non-conjugated triplet 1,2-biradical from β,γ-vinylarylketone

Laser flash photolysis of 2-methyl-1-phenylbut-3-en-1-one (1) conducted at irradiation wavelengths of 266 and 308nm results in the formation of triplet 1,2-biradical 2 that has max at 370 and 480nm. Biradical 2 is formed with a rate constant of 1.1×107s-1 and decays with a rate constant of 2.3×105s-1. Isoprene-quenching studies support the notion that biradical 2 is formed by energy transfer from the triplet-excited state of the ketone chromophore of 1. Density functional theory calculations were used to verify the characterization of triplet biradical 2 and validate the mechanism for its formation. Thus, it has been demonstrated that intramolecular sensitization of simple alkenes can be used to form triplet 1,2-biradicals with the two radical centres localized on the adjacent carbon atoms.

Regioselective allylation reactions using crotyl Grignard reagent-CeCl3 systems

Regioselective allylation reactions using crotyl Grignard reagent-CeCl3 systems are described. Regioselectivity depends on the lanthanide salts: α-product was predominantly produced with light rare earth elements such as La, Ce, Pr, Nd, whereas

Allylation of carbonyl compounds in the presence of catalytic electrogenerated zinc. Unusual regioselectivity with a trifluorinated analog of prenyl bromide

A mild and effective method of electrochemical zinc activation based on the cathodic reduction of a catalytic amount of ZnBr2 in acetonitrile is applied to the coupling of a trifluorinated analog of prenyl bromide with carbonyl compounds and af

Activation of manganese metal by a catalytic amount of PbCl2 and Me3SiCl

Allylation of carbonyl compounds and the Reformatsky-type reaction are performed with manganese metal which is activated by addition of a catalytic amount of Me3SiCl and PbCl2 in THF.

Regioreversed Addition of But-2-enyltributylstannane to Aldehydes in the Presence of Aluminium Chloride-Propan-2-ol

The reaction of but-2-enyltributylstannane with certain aldehydes in the presence of AlCl3-PriOH produces the α-adduct (3) either predominantly or exclusively, while the reaction in the presence of ordinary Lewis acids, such as TiCl4, SnCl4, an

Reduction of monothioacetals with SmI2: Application to [2,3]-Wittig rearrangement

Simple reduction of O,S-acetals with SmI2 yielding ethers with selective liberation of the sulfenyl group can be accomplished using benzene-HMPA with t-BuOH. When O,S-acetals possess an O-allyl group, the [2,3]-Wittig rearrangement yielding homoallyl alcohols follows the elimination of a sulfenyl group. For chemoselective elimination of an alkoxy group to give sulfides, MeOTf serves as a moderately effective additive.

Nickel-catalyzed indium(I)-mediated double addition of aldehydes to 1,3-dienes

In the presence of InI, Ni(acac)2 and PPh3, several 1,3-dienes were reacted with two molecules of aldehyde to give the corresponding 1,4- and 1,6-diols. The regioselectivity of the 1,4-/1,6-diol was efficiently regulated by the addit

Enantioselective allylation of aldehydes promoted by chiral sulfur reagents

The addition of allylzinc bromide to aldehydes was studied with different chiral sulfur compounds acting as a catalyst. Yield differences and enantiomeric excesses were observed.