61979-36-0 Usage
Uses
Used in Organic Synthesis:
(1,2-dibromoethyl)(triphenyl)silane serves as a reagent in various organic synthesis reactions, playing a crucial role in the preparation of silicon-containing polymers. Its unique structure allows it to be a valuable component in the synthesis of complex organic molecules.
Used as a Halogenating Agent:
Due to the presence of bromine atoms, (1,2-dibromoethyl)(triphenyl)silane is utilized as a halogenating agent in chemical reactions, where the introduction of halogen atoms is required for further synthetic steps or to modify the properties of the target molecules.
Used in Cross-Coupling Reactions:
(1,2-dibromoethyl)(triphenyl)silane has been studied for its potential application in cross-coupling reactions, which are fundamental in modern organic chemistry for the formation of carbon-carbon bonds, particularly in the synthesis of pharmaceuticals and advanced materials.
Used as a Source of Silicon-Based Radical:
(1,2-dibromoethyl)(triphenyl)silane is also recognized for its potential as a source of silicon-based radicals, which are important intermediates in various radical reactions and can be used to initiate or propagate radical chain reactions in synthetic chemistry.
Used in the Preparation of Advanced Materials:
Given its stability and reactivity, (1,2-dibromoethyl)(triphenyl)silane is employed in the preparation of advanced materials, including those with unique electronic, optical, or mechanical properties, which can be utilized in high-tech industries.
Check Digit Verification of cas no
The CAS Registry Mumber 61979-36-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,9,7 and 9 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 61979-36:
(7*6)+(6*1)+(5*9)+(4*7)+(3*9)+(2*3)+(1*6)=160
160 % 10 = 0
So 61979-36-0 is a valid CAS Registry Number.
61979-36-0Relevant academic research and scientific papers
Reactions of carboxamides with vinylsilanes under oxidative conditions
Astakhova, Vera V.,Moskalik, Mikhail Yu.,Shainyan, Bagrat A.
, (2022/01/11)
The reactions of acetamide, benzamide and trifluoroacetamide with trimethyl(vinyl)-, triphenyl(vinyl)-, dimethyl(divinyl)- and diphenyl(divinyl)silanes in the presence of oxidants (t-BuOCl + NaI) or N-bromosuccinimide (NBS) in acetonitrile have been studied. Generally, all unsaturated silanes react with trifluoroacetamide to give the products of haloamidation, whereas with acetamide or benzamide the reaction affords mainly the products of halogenation. The formation of bromoamination product containing the MeCONH moiety in the NBS-induced reaction of trimethylvinylsilane with all studied amides clearly indicates that the reaction proceeds with the solvent (MeCN) interception rather than by the attack of the amide nucleophile. The product of bromoamidation from the NBS-promoted reaction undergoes a base-induced cyclization to the corresponding 1,3-oxazoline in quantitative yield.
Copper(I) tert-butoxide-promoted allylation of β-triphenylsilyl allylic alcohols via 1,3 Csp2-to-o silyl migration
Tsubouchi, Akira,Itoh, Miki,Onishi, Kotaro,Takeda, Takeshi
, p. 1504 - 1508 (2007/10/03)
The substitution of the silyl group in vinylsilanes by an allylic group proceeded when β-triphenylsilylallyl alcohols were treated with copper(I) tert-butoxide and allylic halides. This reaction is the first synthetic application of 1,3 Csp2-to-O silyl migration which provides a useful method for generation of vinyl anion equivalents.
