622-14-0

Basic information

• Product Name: N,N-diphenylmethanediamine
• CAS NO: 622-14-0
• Molecular Formula: C₁₃H₁₄N₂
• Molecular Weight: 198.268
• Mol File: 622-14-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 401.2°Cat760mmHg
• Flash Point: 265.2°C
• Density: 1.147g/cm³
• CAS DataBase Reference: N,N-diphenylmethanediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diphenylmethanediamine(622-14-0)
• EPA Substance Registry System: N,N-diphenylmethanediamine(622-14-0)

Safety Data

• Hazardous Substances Data: 622-14-0(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 62-53-3 aniline 
• 75-11-6 diiodomethane 
• 73455-06-8 sulfuric acid chloromethyl ester-methyl ester 
• 88933-19-1 methoxymethylphenylamine 
• 64-17-5 ethanol 
• 7732-18-5 water 
• 5395-50-6 1,3,4,6-tetrakis(hydroxymethyl)tetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione 
• 91-78-1 1,3,5-triphenylhexahydro-1,3,5-triazine 
• 103-70-8 Formanilid 

Downstream Products

• 620-81-5 N,N'-Diphenyloxamid 
• 3526-45-2 2-((phenylamino)methyl)phenol 
• 91-78-1 1,3,5-triphenylhexahydro-1,3,5-triazine 
• 860574-61-4 N,N',N'',N'''-tetraphenyl-N,N''-methanediyl-di-urea 
• 102-08-9 N,N-diphenylthiourea 
• 467-62-9 pararosaniline 
• 101-77-9 4,4'-diamino diphenyl methane 
• 1208-52-2 2,4'-diaminodiphenylmethane 
• 62-53-3 aniline 
• 33033-90-8 N-(4-hydroxylbenzyl)aniline 
• 92292-46-1 3-anilinomethyl-(3ar,7at)-hexahydro-benzooxazole-2-thione 
• 100-62-9 N-methylenebenzenamine 
• 103-01-5 N-Phenylglycine 
• 50-00-0 formaldehyd 

Relevant articles and documents

Tetrakis(hydroxymethyl)glycoluril in N-methylenation reactions with arylamines

[Figure not available: see fulltext.] This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines, based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyd

TRINUCLEAR INTERMEDIATES IN ANILINE-FORMALDEHYDE CONDENSATION

The trinuclear intermediate products 4-(4-anilinomethylanilinomethyl)aniline and 4-aniline were isolated and identified by TLC during investigation of the aniline-formaldehyde condensation in the presence of acidic catalysts.The transformation of these compounds and of 4-anilinomethylaniline in methanol and under the conditions of acid aniline-formaldehyde condensation and rearrangement are described.It was established that the fromation of polyamines is possible not only as a result of the initial reaction of the final diamines with formaldehyde but also of the reaction of protonated anilinomethylanilines with aromatic amines present in the reaction mixture.