62292-09-5

Upstream product

• 58468-95-4 (1,2-dimethyl-allylsulfanyl)-benzene 
• 931-59-9 benzenesulfenyl chloride 
• 63996-47-4 2-hydroxy-2-methyl-3-phenylthiobutane 
• 513-35-9 2-methyl-but-2-ene 
• 54523-03-4 2-p-Tosyloxy-3-methyl-3-phenylsulfinylbutan 

Relevant academic research and scientific papers

FACILE FUNCTIONALIZATION OF THE ISOPROPYLIDENE TERMINUS OF ACYCLIC MONOTERPENES BY WAY OF BENZENESULFENYL CHLORIDE ADDITION

Highly site- and regioselective terminal functionalizations of acyclic monoterpenes 1 via benzenesulfenyl chloride addition followed by hydrolysis assisted by silica gel, dehydrochlorination under neutral or weakly basic condition, or dehydrochlorination by strongly basic treatment respectively providing β-hydroxy sulfides 3, terminal methallylic sulfides 4, or vinylsulfides 5 are developed.Conversion of 4 to terminal trans-allylic alcohols 10 via sulfoxides 9 by the Evans procedure is also described.