63996-47-4

Upstream product

• 513-35-9 2-methyl-but-2-ene 
• 108-98-5 thiophenol 
• 63996-46-3 Phenyl-(2-chlor-1,2-dimethyl)propyl-sulfid 
• 58468-92-1 (2RS)-3-methyl-3-phenylsulfanylbutan-2-ol 
• 35875-02-6 2-methyl-2-phenylsulfanylbutan-3-one 

Downstream Products

• 62292-09-5 2-Methyl-3-phenylsulfinyl-1-buten 
• 58468-99-8 E-2-methyl-1-phenylthio-2-butene 
• 58468-95-4 (1,2-dimethyl-allylsulfanyl)-benzene 

Relevant academic research and scientific papers

N-Phenyltriazolinedione as an initiator in the radical addition of thiophenol to alkenes

N-Phenyltriazolinedione is found to be an efficient initiator in the radical (anti-Markovnikov) addition of thiophenol to 2-methyl-2-butene. A second, minor, product (an alcohol, from oxygen addition) was also obtained, and a possible mechanistic scheme is proposed.