62461-01-2

Basic information

• Product Name: Benzenesulfonic acid, 4-methyl-, (2-methyl-1-phenylpropylidene)hydrazide, (Z)-
• CAS NO: 62461-01-2
• Molecular Formula: C17H20N2O2S
• Molecular Weight: 316.424
• Mol File: 62461-01-2.mol

Chemical Properties

• CAS DataBase Reference: Benzenesulfonic acid, 4-methyl-, (2-methyl-1-phenylpropylidene)hydrazide, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonic acid, 4-methyl-, (2-methyl-1-phenylpropylidene)hydrazide, (Z)-(62461-01-2)
• EPA Substance Registry System: Benzenesulfonic acid, 4-methyl-, (2-methyl-1-phenylpropylidene)hydrazide, (Z)-(62461-01-2)

Safety Data

• Hazardous Substances Data: 62461-01-2(Hazardous Substances Data)

Upstream product

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 85267-80-7 (4-methylpenta-1,3-diene-2,3-diyl)dibenzene 
• 24469-13-4 1-(phenylthio)-2-methyl-1-phenyl-1-propene 
• 4412-08-2 3-methyl-2-phenylbut-2-enoic acid 
• 14161-67-2 1-methyl-4-(2-methyl-1-phenylprop-1-en-1-yl)benzene 
• 51248-21-6 2-(2-methyl-1-phenylprop-1-en-1-yl)thiophene 
• 223914-82-7 C₁₈H₂₀ 
• 1393683-52-7 C₁₈H₂₀ 

Relevant articles and documents

Palladium-Catalyzed One-Pot Synthesis of 5-(1-Arylvinyl)-1H-benzimidazoles: Overcoming the Limitation of Acetamide Partners

A new one-pot palladium-catalyzed process between N-tosylhydrazones, N-(dihalophenyl)-imidates, and amines was designed. This reaction involves Barluenga cross-coupling and N-arylation followed by cyclization to produce functionalized benzimidazoles. Duri

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

The combination of photoredox catalysis with the Wolff-Kishner (WK) reaction allows the difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff-Kishner reaction). Photoredox initiated radical addition to N-sulfonylhydrazones yields α-functionalized carbanions following the WK-type mechanism. With sulfur-centered radicals, the carbanions are further functionalized by reaction with electrophiles including CO2 and aldehydes, whereas CF3 radical addition furnishes a wide range of gem-difluoroalkenes through β-fluoride elimination of the generated α-CF3 carbanions. More than 80 substrate examples demonstrate the broad applicability of this reaction sequence. A series of investigations including radical inhibition, deuterium labeling, fluorescence quenching, cyclic voltammetry, and control experiments support the proposed radical-carbanion relay mechanism.

One-step synthesis of sulfonamides from N-tosylhydrazones

The first described reaction between N-tosylhydrazone and SO2 is reported to provide alkyl sulfonamides in the presence of various amines. In this procedurally simple method, hydrazones of both unsaturated aldehydes and ketones proceed in moder

Iron(III) phthalocyanine-chloride-catalyzed synthesis of sulfones from sulfonylhydrazones

In this study, sulfones are synthesized from sulfonylhydrazones catalyzed by iron(III) phthalocyanine chloride. This reaction offers broad substrate scope, occurs under mild conditions, utilized readily available reactants, and forms products in good-to-h