62477-06-9

Basic information

• Product Name: 1,3-Benzenediamine, 2,4,6-tribromo-
• Synonyms: 2,4,6-tribromo-m-phenylenediamine;1,3-Benzenediamine,2,4,6-tribromo;2,4,6-tribromo-1,3-diaminobenzene;2,4,6-Tribrom-m-phenylendiamin;2.4.6-Tribrom-1.3-diamino-benzol;2,4,6-tribromo-1,3-phenylenediamine
• CAS NO: 62477-06-9
• Molecular Formula: C6H5Br3N2
• Molecular Weight: 344.831
• Mol File: 62477-06-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,3-Benzenediamine, 2,4,6-tribromo-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzenediamine, 2,4,6-tribromo-(62477-06-9)
• EPA Substance Registry System: 1,3-Benzenediamine, 2,4,6-tribromo-(62477-06-9)

Safety Data

• Hazardous Substances Data: 62477-06-9(Hazardous Substances Data)

Usage

General Description

1,3-Benzenediamine, 2,4,6-tribromo- is a chemical compound that consists of a benzene ring with three bromine atoms attached at the 2, 4, and 6 positions. It is commonly used as a flame retardant in various products such as plastics, textiles, and electronic devices. 1,3-Benzenediamine, 2,4,6-tribromo- is known for its ability to reduce the flammability of materials and prevent the spread of fires. However, it has been found to have potential health and environmental risks, including being a possible carcinogen and causing harm to aquatic organisms. Therefore, there is ongoing research and regulatory efforts to better understand and mitigate the potential hazards associated with 1,3-Benzenediamine, 2,4,6-tribromo-.

Upstream product

• 108-45-2 m-phenylenediamine 
• 7732-18-5 water 
• 861081-04-1 N,N'-(4,6-dibromo-m-phenylene)-bis-toluene-4-sulfonamide 
• 55850-21-0 N,N'-bis(3-methylbenzenesulfonyl)m-phenylenediamine 
• 51686-79-4 2,4,6-tribromo-1,3-dinitrobenzene 
• 64-19-7 acetic acid 

Downstream Products

• 98279-03-9 2,4,6-tribromo-3-isocyanato-aniline 
• 108-45-2 m-phenylenediamine 
• 642068-68-6 2,4,6-tribromo-3-propylsulfanyl-phenylamine 

Relevant articles and documents

Supramolecular Assembly of Tris(4-carboxyphenyl)arenes: Relationship between Molecular Structure and Solid-State Catenation Motifs

The crystal structures of seven 1,3,5-tris(4-carboxyphenyl)arenes with functionalized central arene rings are reported. The formation of (6,3) hcb hexagonal sheets as a result of carboxylic acid dimer formation was observed in most of the crystal structures, with the exception of two compounds with functional groups capable of forming hydrogen bonds, namely, 2,4,6-tris(4-carboxyphenyl)-1,3-diaminobenzene and 2,4,6-tris(4-carboxyphenyl)-3-methylaniline. These structures were found to incorporate THF solvent molecules in their hydrogen-bonding motif, giving rise to distorted pseudohexagonal arrays. Functional groups on the central ring were found to influence stacking distances, stacking offsets, inclination angles, degree of catenation, and dimensions of solvent-occupied channels. To better understand and appreciate these complicated crystal structures, they were categorized into four distinct stacking/catenation families: simple stacking, single-layer offset catenation, double-layer offset catenation, and rotated-layer catenation. The unique structure of the unfunctionalized parent compound 1,3,5-tris(4-carboxyphenyl)benzene is rationalized in light of the structural behavior of its derivatives.

Synthesis of aza-m-xylylene diradicals with large singlet-triplet energy gap and statistical analyses of their EPR spectra

We describe synthesis and characterization of a derivative of aza-m-xylylene, diradical 2, that is persistent in solution at room temperature with the half-life measured in minutes (～80-250 s) and in which the triplet ground state is below the lowest sing

A convenient and efficient synthesis of polyphenylmono-, di-, and -triaminobenzenes

A new convenient and efficient synthesis of polyphenylmono- and -diaminobenzenes by the palladium(0)-catalyzed cross-coupling reaction of polyhalomono- and -diaminobenzenes with phenylboronic acid is described. A synthesis of 2,4-diphenyl-1,3,5-triaminobe