62592-69-2Relevant academic research and scientific papers
Photocyclisation of Enamides. Part 24. Total Synthesis of (+/-)-Isofumigaclavine B and (+/-)-Lysergic Acid
Ninomyia, Ichiya,Hashimoto, Chiyomi,Kiguchi, Toshiko,Naito, Takeaki
, p. 941 - 948 (2007/10/02)
Total syntheses of two ergoline-types of alkaloids, (+/-)-isofumigaclavine B (14) (for the first time) and methyl (+/-)-lysergate (21) and methyl (+/-)-isolysergate (22), via a route involving reductive photocyclisation of the enamide (2) followed by glyc
Synthesis of ergot alkaloids from tryptophan
Rebek Jr.,Tai,Shue
, p. 1813 - 1819 (2007/10/02)
The first total syntheses of lysergine and setoclavine are described, as well as a new and efficient synthesis of lysergic acid. The starting material for these syntheses is tryptophan, protected as its dihydro, dibenzoyl derivative. This material is dehy
