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N-Nitrocarbamic acid ethyl ester, also known as ethyl nitrocarbamate, is an organic compound with the chemical formula C3H6N2O4. It is a colorless, oily liquid that is soluble in water and has a molecular weight of 134.09 g/mol. N-Nitrocarbamic acid ethyl ester is synthesized by the reaction of ethyl chloroformate with nitrocarbamic acid, and it is an intermediate in the production of various agrochemicals, such as herbicides and insecticides. Due to its reactivity and potential toxicity, it is important to handle N-nitrocarbamic acid ethyl ester with caution and proper safety measures.

626-37-9

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626-37-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 626-37-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,2 and 6 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 626-37:
(5*6)+(4*2)+(3*6)+(2*3)+(1*7)=69
69 % 10 = 9
So 626-37-9 is a valid CAS Registry Number.
InChI:InChI=1/C3H6N2O4/c1-2-9-3(6)4-5(7)8/h2H2,1H3,(H-,4,6,7,8)/p+1

626-37-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl N-nitrocarbamate

1.2 Other means of identification

Product number -
Other names T3589

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:626-37-9 SDS

626-37-9Relevant academic research and scientific papers

Nitrimines: VII. Reaction of S,S′-Dimethyl-N-nitroimidodithiocarbonate with Alkali. Synthesis of S-Methyl-N-nitrothiocarbamate and Its Salts

Astakhov,Antishin,Nefedov,Salnikov,Buka

, p. 1638 - 1642 (2018)

Reaction of S,S′-dimethyl-N-nitroimidodithiocarbonate with alkali in aqueous-alcoholic solution results in salts of S-methyl-N-nitrothiocarbamate. In anhydrous ethanol a salt of nitrouretane is obtained. By the reaction of S-methyl-N-nitrothiocarbamate salts with hydrazine 4-nitrosemicarbazide salts were prepared.

Dinitramide and its salts 10. * synthesis of dinitramide salts from N,N-dinitro derivatives of organic amides

Luk'yanov,Kozlova,Shitov,Konnova,Kalinina,Tartakovsky

, p. 863 - 867 (1996)

N,N-Dinitro derivatives of alkylurethanes, benzamide, and p-toluenesulfamide were synthesized for the first time. Their reactions with ammonia afforded the ammonium salt of dinitramide in 44-85 % yields.

Chemistry of urea nitro derivatives: III. Reactions of N,N′ -dinitrourea with bases

Il'yasov,Lobanova,Popov,Sataev

, p. 1731 - 1738 (2002)

N,N′-Dinitrourea reacts with bases to form the corresponding acid or neutral salts. Its reaction with hydrazine yields 4-nitrosemicarbazide, and the reaction with hydroxylamine leads to N-hydroxy-N′-nitrourea.

Activation of nitrogen bronsted acids: Synthesis and reactivity of a new class of nitrogen acid complexes

Bohle, D. Scott,Chua, Zhijie

, p. 11160 - 11172 (2014)

The nitrogen acids RC(O)NHNO2, N-nitroamide, R = CH3 (1), C2H5 (2) and N-nitrocarbamate, R′OC(O)NHNO2, R′ = CH3 (3), C2H5 (4) are a class of primary N-nitrocarboxamide compounds that oxidatively add to trans-Ir(I)(Cl)(N2)(PPh3)2 to give six-coordinate Ir(III)(η2-(NO2)-nitrogen acid)(H)(Cl)(PPh3)2 complexes 5-8. Unexpected fluxional behavior of the complexes in solution is observed by 1H NMR spectroscopy. Reaction intermediates of the oxidative addition reactions were also observed and monitored using 31P and 1H NMR and solution IR spectroscopies. Complex 5 reacts with methyl triflate in CH3CN to generate bis(acetonitrile) complex (9) from a net loss of the nitrogen acid anion. P(CH3)2Ph reacts with 5 to give phosphine-substituted and P(CH3)2Ph addition isomers (10). Reactivity studies of 5 with CO gave metastable CO adduct isomer 11, which loses CO on prolonged standing in solution. (Chemical Equation Presented).

Chemistry of urea nitro derivatives: II. Synthesis of nitramide from N,N′-dinitrourea. New reactions of nitramide

Lobanova,Il'yasov,Popov,Sataev

, p. 1 - 6 (2007/10/03)

Study of the hydrolysis of N,N′-dinitrourea resulted in the development of convenient procedures for synthesizing nitramide on the basis of urea. New reactions of nitramide were examined.

Process for producing an aromatic urethane

-

, (2008/06/13)

An aromatic urethane is obtained at high yield without involving corrosion of a stainless steel reactor by interacting an aromatic nitro compound, an organic compound having at least one hydroxyl group therein and carbon monoxide in the presence of a cata

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