626200-80-4

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-deoxy-3-C-ethyl-α-D-altropyranoside
• Synonyms: methyl 4,6-O-benzylidene-3-deoxy-3-C-ethyl-α-D-altropyranoside
• CAS NO: 626200-80-4
• Molecular Weight: 294.348
• Mol File: 626200-80-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-deoxy-3-C-ethyl-α-D-altropyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-deoxy-3-C-ethyl-α-D-altropyranoside(626200-80-4)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-deoxy-3-C-ethyl-α-D-altropyranoside(626200-80-4)

Safety Data

• Hazardous Substances Data: 626200-80-4(Hazardous Substances Data)

Upstream product

• 557-18-6 diethylmagnesium 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 2386-64-3 ethylmagnesium chloride 
• 75-00-3 chloroethane 

Downstream Products

• 626200-85-9 Benzoic acid (1R,2S,3S)-2-ethyl-3,4-dihydroxy-1-vinyl-butyl ester 
• 626200-88-2 Benzoic acid (1R,2R)-2-(S)-oxiranyl-1-vinyl-butyl ester 
• 626200-83-7 Benzoic acid (2S,3S,4S,5S,6S)-2-bromomethyl-4-ethyl-5-hydroxy-6-methoxy-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

Synthesis of A-ring synthon of 2α-substituted vitamin d3 analogues utilizing Grignard reaction towards methyl 2,3-anhydro-4,6-o-benzylidene-α-D-manno-pyranoside

A concise route to the Trost A-ring precursor enyne for synthesizing 2α-substituted 1α,25-dihydroxyvitamin D3 (1) is described, in which the 2α-substituents could be introduced via addition reaction of Grignard reagent towards the sugar epoxide