62662-80-0Relevant academic research and scientific papers
Synthesis and characterization of some arene hydrido-complexes 6-arene)(EPh3)2H>+ (η6-arene = benzene, p-cymene or hexamethylbenzene; E = P, As or Sb). Crystal structure of 6-C6H6)(PPh3)2H>BF4
Sisodia, Om Singh,Sahay, A. N.,Pandey, D. S.,Agarwala, U. C.,Jha, N. K.,et al.
, p. 35 - 40 (2007/10/03)
6-arene)Cl2)2> (η6-arene = benzene, p-cymene or hexamethylbenzene) reacts with EPh3 (E = P, As or Sb) in methanol to give monomeric cationic arene hydrido complexes 6-arene)(EPh3)2H>+ in presence of AgBF4 or AgPF6.However, reactions in presence of triphenylphosphine also yield a symmetrically bridged tris (μ-methoxy) complex +.The crystal structure of 6-C6H6)(PPh3)2H>BF4 has been determined.Crystal data, monoclinic system, space group P21/n, a=14.792 (2) Angstroem; b=14.351 (1) Angstroem; c=17.661 (2) Angstroem; β=102.25 (1) deg and Z=4.Crystal structure determination reveals the distortion of the Ru(PPh3)2H+ unit in the cation 6-C6H6)(PPh3)2H>+. - Keywords: Arene hydrido complexes; Ruthenium; Phosphine; Arsine; Stibine
