62697-75-0

Upstream product

• 24041-60-9 (+)-isopinocampheol 
• 98-59-9 p-toluenesulfonyl chloride 
• 1196-00-5 (-)-isopinocampheol 
• 2734-31-8 (1R,2R,3S,5S)-(+)-neoisopinocampheol 
• 51152-11-5 (1R*,2R*,3R*,5S*)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol 

Downstream Products

• 7785-70-8 (+)-α-pinene 
• 24031-99-0 (-)-trans-δ-pinene 
• 24031-98-9 (1S,4S,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-2-ene 
• 35182-62-8 (1S,2S,5R,7S)-2,8,8-trimethyl-3-azatricyclo[5.1.1.0^2,5]nonan-4-one 
• 49751-98-6 (1R,4R,5S)-4,6,6-trimethylbicyclo[3.1.1]hept-2-ene 
• 1000304-34-6 (1R,2R,5S,6R,7R)-6,8,8-trimethyl-3-azatricyclo[5.1.1.0^2,5]nonan-4-one 
• 80-56-8 Pinene 
• 79-92-5 camphene 
• 14576-08-0 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene 
• 38988-92-0 pinan-2β-yl methyl ether 
• 38988-92-0 pinan-2α-yl methyl ether 
• 138-86-3 limonene. 

Relevant academic research and scientific papers

Regio- and stereoselective synthesis of the enantiomers of monoterpene-based β-amino acid derivatives

The regio- and stereospecific addition of chlorosulfonyl isocyanate to cis-δ-pinene enantiomers has furnished monoterpene-fused β-lactams. The observed regioselectivity can be explained by ab initio DFT modeling of transition state structures. In contrast with the less reactive α-pinane-fused β-lactam 4, the resulting β-lactams 5 and 13 containing an amino group connected to a secondary carbon possess similar reactivity to the cycloalkane-fused analogues and can be easily converted to the β-amino acid and its protected derivatives. The base-catalyzed isomerization of the cis-amino ester afforded the corresponding trans-amino ester in moderate yield.

Syntheses and reactions of new optically active terpene dialkyl diselenides

The reaction of sodium diselenide with optically active alkyl tosylates or chlorides is found to be a useful method for the synthesis of optically active dialkyl diselenides. Optically active monoterpene diselenides derived from menthane, carane, pinane,

Rearrangement of Pinane Derivatives. Part 8. Deamination of 2αH-Pinan-3α-ylamine

Solvolysis of 2αH-pinan-3α-yl toluene-p-sulphonate has been shown to proceed with concomitant 1,2-hydride shift to give the pinan-2-yl carbocation.Contrary to earlier reports, this species reacts normally to give, in good yield, pinan-2-yl substitution products.In contrast the pinan-3-ylamines react via a similar route, but give much smaller amounts of pinan-2-yl products.The usual reasons for differences between solvolysis and deamination (i.e. the intermediacy of diazonium ions and/or high-energy ions) can be discounted, and possible reasons for the differences in behaviour are discussed.