62731-48-0Relevant academic research and scientific papers
Synthesis of Fluorenes with an All-Carbon Quaternary Center via Palladium-Catalyzed Dual Arylation using Cyclic Diaryliodonium Triflates
Peng, Xiaopeng,Luo, Hongwen,Wu, Fuhai,Zhu, Daqian,Ganesan,Huang, Peng,Wen, Shijun
, p. 1152 - 1156 (2017)
Catalyzed by palladium species, cyclic diaryliodonium salts underwent dual C-aryl functionalization smoothly with activated methylene sources. With this new finding, a series of diversified fluorenes with an all-carbon quaternary center was quickly constructed. Moreover, our approach also provided various novel spirofluorenes containing barburate acid or indane motifs which are featured in medicinal drugs and functional materials. (Figure presented.).
