62733-86-2Relevant academic research and scientific papers
Chemical Transformation of Terpenoids. VII. Syntheses of Chiral Segments, Key Building-Blocks for the Right Half of Taxane-Type Diterpenoids
Shibuya, Hirotaka,Tsujii, Shinji,Yamamoto, Yoshio,Miura, Hiromi,Kitagawa, Isao
, p. 3417 - 3427 (2007/10/02)
Two kinds of chiral segments, i.e. segment B-I (4) and segment B-II (5), which are potentially versatile building-blocks for construction of the right half of taxane-type diterpenoids, were synthesized from 3-methyl-2-cyclohexen-1-one (6) via optical reso
Regioselectivity in the Intramolecular Carbon-Hydrogen Insertion in Metal-catalysed Decomposition of some cis-1-Methyl-3-arylcyclohexyl Diazomethyl Ketones. A Highly Efficient Homogeneous Nickel Catalyst for Carbenoid Insertion
Chakraborti, Asit K.,Ray, Jayanta K.,Kundu, Kalyan K.,Chakrabarty, Sephali,Mukherjee, Debabrata,Ghatak, Usha Ranjan
, p. 261 - 273 (2007/10/02)
The comparative effectiveness of a variety of copper catalysts and a few transition-metal chelates have been examined in the carbenoid decomposition of cis,cis-1,5-dimethyl-3-phenylcyclohexyl diazomethyl ketone (11),
ELECTROCHEMICAL CARBOXYLATION OF alpha , beta -UNSATURATED KETONES WITH CARBON DIOXIDE.
Harada,Sakakibara,Kunai,Sasaki
, p. 611 - 612 (2007/10/02)
Several aromatic and aliphatic alpha , beta -unsaturated ketones were converted to the corresponding gamma -keto acids by the electrochemical reduction in acetonitrile in the presence of CO//2. The yields of the keto acid were 73-82% when the enones have at least one aromatic substituent. In the case of aliphatic enones, the yields of the carboxylation reaction were 67% for 2-cyclohexen-1-one and 44% for 3-buten-2-one.
