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N-octylformamide is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 6282-06-0 Structure
  • Basic information

    1. Product Name: N-octylformamide
    2. Synonyms: N-octylformamide;N-n-OctylforMaMide;N-n-Octylformamide
    3. CAS NO:6282-06-0
    4. Molecular Formula: C9H19NO
    5. Molecular Weight: 157.25
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 6282-06-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 291°C(lit.)
    3. Flash Point: 161.4°C
    4. Appearance: /
    5. Density: 0.858g/cm3
    6. Vapor Pressure: 0.00421mmHg at 25°C
    7. Refractive Index: 1.4490-1.4530
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: N-octylformamide(CAS DataBase Reference)
    11. NIST Chemistry Reference: N-octylformamide(6282-06-0)
    12. EPA Substance Registry System: N-octylformamide(6282-06-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 6282-06-0(Hazardous Substances Data)

6282-06-0 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 34, p. 3204, 1969 DOI: 10.1021/jo01262a093

Check Digit Verification of cas no

The CAS Registry Mumber 6282-06-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,2,8 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6282-06:
(6*6)+(5*2)+(4*8)+(3*2)+(2*0)+(1*6)=90
90 % 10 = 0
So 6282-06-0 is a valid CAS Registry Number.
InChI:InChI=1/C9H19NO/c1-2-3-4-5-6-7-8-10-9-11/h9H,2-8H2,1H3,(H,10,11)

6282-06-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name N-Octylformamide

1.2 Other means of identification

Product number -
Other names N-n-octyl carboxamide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6282-06-0 SDS

6282-06-0Relevant articles and documents

Light-Activated Sensitive Probes for Amine Detection

Valderrey, Virginia,Bonasera, Aurelio,Fredrich, Sebastian,Hecht, Stefan

, p. 1914 - 1918 (2017/02/05)

Our new, simple, and accurate colorimetric method is based on diarylethenes (DAEs) for the rapid detection of a wide range of primary and secondary amines. The probes consist of aldehyde- or ketone-substituted diarylethenes, which undergo an amine-induced decoloration reaction, selectively to give the ring-closed isomer. Thus, these probes can be activated at the desired moment by light irradiation, with a sensitivity that allows the detection of amines at concentrations as low as 10?6m in solution. In addition, the practical immobilization of DAEs on paper makes it possible to detect biogenic amines, such as cadaverine, in the gas phase above a threshold of 12 ppbv within 30 seconds.

Catalytic synthesis of silyl formates with 1 atm of CO2 and their utilization for synthesis of formyl compounds and formic acid

Itagaki, Shintaro,Yamaguchi, Kazuya,Mizuno, Noritaka

, p. 347 - 352 (2013/02/22)

In the presence of simple Rh2(OAc)4 and K 2CO3, the hydrosilylation of CO2 (1 atm) with various hydrosilanes efficiently proceeded to afford the corresponding silyl formates in moderate to high yields (53-90% yields). By using the dimethylphenylsilyl formate produced by the hydrosilylation, formamides, formic acid, and a secondary alcohol (via an aldehyde) could be synthesized by the reaction with various nucleophilic reagents such as amines, aniline, water, and the Grignard reagent.

Amides as Nucleophiles: Reaction of Alkyl Halides with Amides or with Amides and Water. A New Look at an Old Reaction

Brace, Neal O.

, p. 1804 - 1811 (2007/10/02)

Heating of formamide with an alkyl halide (with or without water) affords a mild, nonhydrolytic, high-yield synthesis of alcohols and formate esters.Yet the way in which substitution on the alkyl halide actually occurs remains obscure.To explore this question, thermal reaction of 1-bromooctane (1a) with formamides (HC(O)NHR, R=H, Me; 2a, 2b) was studied quantitatively.Major products are 1-octanol (3) and n-octyl formate (5); minor products are 1-octene (4), di-n-octyl ether (6), and N-octylformamide (7, from 2a, only).Solid coproduct is HC(=NR)NHR + Br(1-) (e.g., 8a, R=H, methanimidamide hydrobromide).Analogously, 1a and N-methylformamide (2b) give alkylated products 3,5, and 6 along with 8b (R=Me). 1-Iodooctane (1b) reacts similarly.Probe samples show that 1-octanol (3) is first formed, followed by 5 and 6.Occurence of 8a-c is key to a mechanistic interpretation of the reaction.An imidate ("salt I"), e.g., from 1a and 2b, is first formed and reacts with amide 2b to give and 3.Now alcohol 3 is converted to ester 5 and 8b by reaction with this same formylamidine.Water, if present, adds to the imidate and gives a new tetrahedral intermediate that cleaves to ester 5 and amide salt, RNH3X.Analogous reaction steps are proposed to generate side products 4, 6, and 7.Alkylation of formamide by C6F13CH2CH2I (1c) is considerably slower and less efficient than alkylation by 1-bromooctane.This result stands in sharp contrast to fast, efficient reaction of 1c with N-methylformamide or with DMF and water.

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