62867-75-8Relevant academic research and scientific papers
Synthesis of Globotriaosylceramide (Gb3) and Isoglobotriaosylceramide (isoGb3)
Qiu, Dongxu,Schmidt, Richard R.
, p. 217 - 224 (2007/10/02)
The synthesis of globotriaosylceramide (1) was based on O-galactosyl trichloroacetimidate 5α as donor and 4b-O-unprotected lactose 7 as acceptor; 7 was readily accessible from lactose.Glycosylation by an "inverted procedure" afforded preferentially the α-
Building Units of Oligosaccharides, XXXVI. - Investigation of Reactivity in Tri-and Pentasaccharide Syntheses. Improved Synthesis of the Pentasaccharide Chain of the Forssman Antigen
Paulsen, Hans,Buensch, Almuth
, p. 2204 - 2215 (2007/10/02)
The dependence of selectivity and yield upon the initial saccharide's reactivity is shown for the syntheses of the trisaccharides 7, 8, 9, and 12.From 8 comes the trisaccharide halide 15 which, together with 22 in a block synthesis, yields the pentasaccha
