629-70-9Relevant articles and documents
Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents
Chang, Ting-Shuo,Chen, Jyun-Siao,Hsieh, Ya-Chi,Hsu, Hsiao-Lin,Huang, Po-Hsun,Liu, Jen-Wei,Liu, Yu-Hao,Luo, Shun-Yuan,Wu, Hsin-Ru,Wu, Ren-Tsung,Zhang, Kai-Min
supporting information, (2021/12/02)
Trimethylsilyl esters, AcOTMS, BzOTMS, TCAOTMS, etc., are inexpensive and chemically stable reagents that pose a negligible environmental hazard. Such compounds prove to serve as efficient dualpurpose reagents to respectively achieve acylation and trimethylsilylation of alcohols under acidic or basic conditions. Herein, a detailed study on protection of various substrates and new methodological investigations is described.
Sustainable Method for the Large-Scale Preparation of Fe3O4 Nanocrystals
Lee, SungWoo,Yoon, Jae-Sik,Kang, Sungkyoung,Kwon, Kihyun,Chang, Ki Soo,Lee, SangGap,Choi, Sang-Il,Jeong, Jong-Ryul,Lee, Gaehang,Nam, Ki Min,Davies
, p. 2578 - 2584 (2016/08/05)
In this work, a facile synthetic process is reported for the large-scale synthesis of Fe3O4 nanocrystals. Thermal decomposition of Fe(acac)3 (100 g) in 1-hexadecanol produced Fe3O4 nanocrystals with well-controlled sizes and morphologies. The nanocrystals were spherically shaped with average diameters of 7.8 ± 0.6, 6.5 ± 0.4, and 5.9 ± 0.2 nm when prepared at 300°C, 270°C, and 250°C, respectively. Mechanisms of crystal formation were elucidated on the basis of gas chromatography-mass spectroscopy analysis, enabling the large-scale preparation of Fe3O4 nanocrystals. To provide an environmentally benign route, Fe3O4 nanocrystals were prepared with recycled solvent which was recovered from the initial experiment. The resulting porous Fe3O4 nanocrystals had larger average sizes than those of the initial nanocrystals. Structural characterization was performed using transmission electron microscopy and powder X-ray diffraction.
In situ generated Ph3P(OAc)2as a novel reagent for the efficient acetylation of alcohols and thiols at room temperature
Iranpoor, Nasser,Firouzabadi, Habib,Elham, Etemadi Davan
, p. 1813 - 1816 (2013/04/24)
Ph3P, Br2, and ammonium acetate are used for the in situ generation of Ph3P(OAc)2, which was characterized by different NMR techniques. The Ph3P(OAc)2generated was used as a novel and efficient reagent for the acetylation of alcohols and thiols in acetonitrile at room temperature under homogeneous conditions. This reaction was also performed under heterogeneous conditions using 1,3,2,4- diazadiphosphetidine as an easily prepared, stable, and heterogeneous P(III) compound.