6293-68-1

Usage

Uses

Used in Chemical Synthesis:
4,4'-Dimethyldiphenyliodonium is utilized as a strong oxidizing agent in various chemical synthesis processes. Its ability to oxidize a broad spectrum of organic and inorganic substrates makes it a valuable component in the production of different compounds.
Used in Research Applications:
In the field of scientific research, 4,4'-Dimethyldiphenyliodonium serves as a crucial reagent for conducting experiments that involve oxidation reactions. Its strong oxidizing capabilities facilitate the exploration of new chemical pathways and the development of novel compounds.
Used in Environmental Remediation:
4,4'-Dimethyldiphenyliodonium may be employed in environmental remediation efforts, particularly in the treatment of contaminated water or soil. Its oxidizing properties can help break down pollutants and restore the natural balance of ecosystems.
Used in Pharmaceutical Development:
Although information is limited, 4,4'-Dimethyldiphenyliodonium could potentially be used in the development of pharmaceuticals, particularly in the synthesis of new drug molecules. Its strong oxidizing properties may contribute to the creation of innovative therapeutic agents.

InChI:InChI=1/C14H14I.BrH/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;/h3-10H,1-2H3;1H/q+1;/p-1

Upstream product

• 108-88-3 toluene 
• 624-31-7 4-tolyl iodide 
• 106-38-7 para-bromotoluene 
• 19028-26-3 4-dichloroiodanyl-toluene 

Downstream Products

• 109687-36-7 5-Benzyl-2,2-dimethyl-5-p-tolyl-[1,3]dioxane-4,6-dione 
• 76570-58-6 2-(N-acetyl-N-methylamino)-5-methylphenol 
• 76570-57-5 2-(N-t-butyloxycarbonyl-N-methylamino)-5-methylphenol 
• 77196-48-6 4,5-Dioxo-1-p-tolyl-cyclopentane-1,3-dicarboxylic acid diethyl ester 
• 20876-81-7 p-tolyl benzodithioate 
• 120951-28-2 4-Methyl-dithiobenzoic acid p-tolyl ester 
• 120951-31-7 2-Methyl-dithiobenzoic acid p-tolyl ester 
• 21856-94-0 di-p-tolyl diselenide 
• 90368-33-5 2,2-dimethyl-1,3-dioxane-4,5,6-trione 5-O-p-tolyloxime 
• 120951-33-9 Naphthalene-2-carbodithioic acid p-tolyl ester 
• 109720-11-8 Benzyl-methyl-dithiocarbamic acid p-tolyl ester 
• 109687-43-6 2,2-Dimethyl-5-((Z)-3-phenyl-allyl)-5-p-tolyl-[1,3]dioxane-4,6-dione 
• 591-50-4 iodobenzene 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 

Relevant academic research and scientific papers

CuBr catalyzed C-N cross coupling reaction of purines and diaryliodonium salts to 9-arylpurines

CuBr was found to be an efficient catalyst for the C-N cross coupling reaction of purine and diaryliodonium salts. 9-Arylpurines were synthesized in excellent yields with short reaction times (2.5 h). The method represents an alternative to the synthesis of 9-arylpurines via Cu(ii) catalyzed C-N coupling reaction with arylboronic acids as arylating agents. The Royal Society of Chemistry 2011.

Facile syntheses of symmetrical diaryliodonium salts from various arenes, with sodium metaperiodate as the coupling reagent in acidic media

An easy, inexpensive, safe, and effective preparative procedure to obtain symmetrical diaryliodonium bromides (in 17-88% crude yields) from various arenes is presented in this paper. A novel method for the in situ preparation of iodosyl sulfate (Chretien's reagent) is given. Eleven exemplary crude diaryliodonium bromides were readily oxidatively metathesized with 40% aqueous tetrafluoroboric acid and 30% aqueous hydrogen peroxide (in boiling acetone, used both as a solvent and 'halogen scavenger') to give pure diaryliodonium tetrafluoroborates in 15-85% yields. Georg Thieme Verlag Stuttgart.

Method for preparing diaryl iodonium salts

Provided is a method for preparing diaryl iodonium salts represented by the formula: wherein Ar1 and Ar2 respectively are an aryl group which may be substituted with an electron donor group and which may be the same or different which comprises subjecting a compound represented by the formula Ar1 --H wherein Ar1 is as defined above and a compound Ar2 --I wherein Ar2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20° to +35° C.