62995-09-9Relevant articles and documents
Iron(II)-mediated nitrene transfer from t-butyloxycarbonyl azide (BocN3) to sulfoxides, sulfides, and ketene acetals
Bach, Thorsten,Koerber, Christina
, p. 5015 - 5016 (1998)
The nitrene transfer from t-butyloxycarbonyl azide (BocN3) to several nucleophiles is promoted by ferrous chloride (FeCl2) and yields the corresponding N-Boc protected sulfoximides, sulfimides, or α-amino alkanoates. Whereas the sulf
The preparation of N-tert-butyloxycarbonyl-(Boc-)protected sulfoximines and sulfimines by an iron(II)-mediated nitrene transfer from BocN3 to sulfoxides and sulfides
Bach, Thorsten,Koerber, Christina
, p. 1033 - 1039 (2007/10/03)
The imidation of sulfides and sulfoxides to the corresponding sulfimides and sulfoximides was carried out with N-tert-butyloxycarbonyl azide (BocN3) in the presence of FeCl2. Sulfoxides 1 reacted at room temperature in CH2