Iron(II)-mediated nitrene transfer from t-butyloxycarbonyl azide (BocN3) to sulfoxides, sulfides, and ketene acetals

DOI: 10.1016/S0040-4039(98)00927-7

Source and publish data:

Tetrahedron Letters p. 5015 - 5016 (1998)

Update date:2022-08-16

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Authors:

Bach, Thorsten

Koerber, Christina

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Article abstract of DOI:10.1016/S0040-4039(98)00927-7

The nitrene transfer from t-butyloxycarbonyl azide (BocN₃) to several nucleophiles is promoted by ferrous chloride (FeCl₂) and yields the corresponding N-Boc protected sulfoximides, sulfimides, or α-amino alkanoates. Whereas the sulf

Full text of DOI:10.1016/S0040-4039(98)00927-7

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