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6302-94-9

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6302-94-9 Usage

Uses

Dihydro-5-methyl-4H-1,3,5-dithiazine is used as a reagent in the synthesis of neovibsanin derivatives which have the ability to induce neuronal differentiation in PC12 cells.

Check Digit Verification of cas no

The CAS Registry Mumber 6302-94-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,0 and 2 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 6302-94:
(6*6)+(5*3)+(4*0)+(3*2)+(2*9)+(1*4)=79
79 % 10 = 9
So 6302-94-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H9NS2/c1-5-2-6-4-7-3-5/h2-4H2,1H3

6302-94-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-methyl-1,3,5-dithiazinane

1.2 Other means of identification

Product number -
Other names EINECS 228-598-0

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6302-94-9 SDS

6302-94-9Relevant articles and documents

Mono- and di-alkyl-[1,3,5]-dithiazinanes and their N-borane adducts revisited. Structural and theoretical study

Flores-Parra, Angelina,Guadarrama-Pérez, Carlos,Ruiz, Juan Carlos Gálvez,Sánchez Ruiz, Sonia A.,Suarez-Moreno, Galdina V.,Contreras, Rosalinda

, p. 149 - 159 (2013/10/22)

Structural analyses of a series of 5-alkyl-[1,3,5]-dithiazinanes [R = Me (1), iPr (2), tBu (3)], their N-BH3 adducts (1BH3-3BH3) and their 2-alkyl (R0) derivatives are reported: R = Me, R0 = Me (7); R = Me, R0 iPr (8); R = iPr, R0 =Me (10); R = tBu, R0 =Me (11); and R = Me, R0 = nBu (12). The reaction of 2-lithium-5-methyl-[1,3,5]-dithiazinane (4) with I2 affords the bis-(5-methyl-[1,3,5]-dithiazinan-2-yl) (13). Isostructural compounds: [2,5,5]-trimethyl-[1,3,5]-dithiazinan-5-ium iodide (14), 5-borane-2,5-dimethyl- [1,3,5]-dithiazinane (15) and 2,5,5-trimethyl-[1,3,5,6]-dithiazaborata (16) are compared. Structures of 7, 8 and 10-13 were determined by 11B, 13C and 1H NMR and the X-ray diffraction analyses of 2, 1BH3, 13 and 14 are reported. Optimization of two chair conformers of heterocycles 1-3, 1BH3-3BH3, 7, 9 (R = Me, R0 = tBu), 13-16 were performed by HF/6-31++G and B3LYP/6-31G(d,p) methods and their minimum energy is compared. 2-Alkyl substituents or N-BH3 anchor the [1,3,5]-dithiazinane ring conformation allowing the analyses of steric and electronic interactions as well as the lone pairs effect in these molecules.

Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide

Akhmetova,Nadyrgulova,Tyumkina,Starikova,Antipin,Kunakova,Dzhemilev

, p. 918 - 925 (2008/03/11)

Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3:2:1 give 47-73% of N-hydroxy(or hydroxyalkyl)-1,3,5-dithiazinanes. The reactions of CH2O with H 2S and hydroxylamine or α-amino alcohols at a ratio of 4:3:1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH2O and H2S under analogous conditions only at the amino group to form 4-(1,3,5-dithiazinan- 5-yl)butan-1-ol.

New 1,3,5-heterocyclohexanes: Dioxazines, oxadiazines, thiadiazines, oxathiazines and triazines and their amination, transamination and disproportionation reactions

Flores-Parra, Angelina,Sanchez-Ruiz, Sonia A.

, p. 2079 - 2092 (2007/10/03)

New 1,3,5-heterocyclohexanes: 5-alkyl-1,3,5-dioxazines (R= iPr, tBu and [R]-α-methylbenzyl), 3,5-di([R]-α-methylbenzyl)-1,3,5-oxadiazine, 3,5- di([R]-α-methylbenzyl)-1,3,5-thiadiazine, 5-isopropyl-1,3,5-oxathiazine, 1- isopropyl-3,5-dimethyl-1,3,5-triazine, 1-tert-butyl-3,5-dimethyl-1,3,5- triazine are reported. Amination and transamination reactions of 1,3,5- heterocyclohexanes were investigated. Equilibria between different heterocycles were found. 13C NMR studies allowed to observe new 1,3,5- heterocycles: 1,3,5-triazines bearing two different alkyl substituents, 3,5- ditert-butyl-1,3,5-thiadiazine, 3-tert-butyl-5-isopropyl-1,3,5-oxadiazine. 1,3,5-heterocyclohexanes present a ring fluxional behavior, the ring inversion energy was calculated for dioxazines, oxadiazine, thiadiazines and triazines.

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