630402-80-1

Basic information

• Product Name: 1-methyl-1-(α-styrenyl)siletane
• Synonyms: 1-methyl-1-(α-styrenyl)siletane
• CAS NO: 630402-80-1
• Molecular Weight: 188.345
• Mol File: 630402-80-1.mol

Chemical Properties

• CAS DataBase Reference: 1-methyl-1-(α-styrenyl)siletane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-1-(α-styrenyl)siletane(630402-80-1)
• EPA Substance Registry System: 1-methyl-1-(α-styrenyl)siletane(630402-80-1)

Safety Data

• Hazardous Substances Data: 630402-80-1(Hazardous Substances Data)

Upstream product

• 67300-99-6 1-phenylethenylmagnesium bromide 
• 2351-34-0 1-chloro-1-methylsiletane 

Downstream Products

• 98-85-1 1-Phenylethanol 
• 630402-81-2 1-methyl-1-(sec-phenethyl)siletane 
• 98-86-2 acetophenone 

Relevant articles and documents

Oxidation of Carbon-Silicon Bonds: The Dramatic Advantage of Strained Siletanes

(Matrix presented) Herein we report on the use of siletanes as substrates for the oxidation of carbon-silicon bonds. These tetraalkylsilanes are easy to handle yet susceptible to rapid ring opening and oxidation upon exposure to aqueous fluoride and peroxide. This combination of stability and reactivity presents many practical benefits, including compatibility with silicon protecting groups and electron-rich aromatic rings.

Iridium-Catalyzed Enantioselective Hydrogenation of Vinylsilanes

We have screened a diverse array of iridium complexes derived from chiral N,P ligands as catalysts for the asymmetric hydrogenation of vinylsilanes, a transformation for which generally applicable catalysts were lacking. Several catalysts emerged from thi