63094-12-2

Basic information

• Product Name: Benzoic acid, 2-[[2-(acetylamino)phenyl]thio]-
• CAS NO: 63094-12-2
• Molecular Formula: C15H13NO3S
• Molecular Weight: 287.339
• Mol File: 63094-12-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-[[2-(acetylamino)phenyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-[[2-(acetylamino)phenyl]thio]-(63094-12-2)
• EPA Substance Registry System: Benzoic acid, 2-[[2-(acetylamino)phenyl]thio]-(63094-12-2)

Safety Data

• Hazardous Substances Data: 63094-12-2(Hazardous Substances Data)

Upstream product

• 54920-98-8 2-((2-aminophenyl)thio)benzoic acid 
• 108-24-7 acetic anhydride 
• 114724-41-3 2-(2-aminophenylthio)benzoic acid hydrochloride 
• 4892-02-8 Methyl thiosalicylate 
• 88-73-3 2-Chloronitrobenzene 
• 19806-43-0 2?(2?nitrophenylsulfanyl)benzoic acid 

Downstream Products

• 161146-33-4 2-(2-acetylaminophenylsulfinyl)benzoic acid 

Relevant articles and documents

CONVERSION OF A DIARYLSULFOXIDE TO CYCLIC SULFONIUM YLIDE: DEHYDRATION WITH SIGMA-BOND SHIFT AND DECARBOXYLATION

2-(2-Acetylaminophenylsulfinyl)benzoic acid (4) has been converted to acyl-stabilized cyclic sulfonium-ylide (5) by heating with trifluoroacetic anhydride in DMF.The structure of the product has been determined by X-ray diffraction.The sulfurane-like configuration and the solid-state conformation revealing sulfur-oxygen close contacts are discussed.A mechanism is proposed for the dehydration reaction involving sigma-bond shift and decarboxylation.