6312-20-5Relevant academic research and scientific papers
Synthesis of 1,3-Diketones and β-Keto Thioesters via Soft Enolization
Aderibigbe, Sabrina O.,Coltart, Don M.
, p. 9770 - 9777 (2019/08/27)
Ketones and thioesters undergo soft enolization and acylation using crude acid chlorides on treatment with MgBr2·OEt2 and i-Pr2NEt to give 1,3-diketones and β-keto thioesters, respectively. The use of crude acid chlorides adds efficiency and cost reduction by avoiding the need to purify and/or purchase them. The process is conducted in a direct fashion that does not require prior enolate formation, further enhancing its efficiency and making it very easy to carry out. The method is suitable for large scale applications. ?
Substituent regulated photoluminescent thermochromism in a rare type of octahedral Cu4I4 clusters
Yu, Ya-Dong,Meng, Ling-Bin,Chen, Qiu-Cheng,Chen, Guang-Hui,Huang, Xiao-Chun
supporting information, p. 8426 - 8437 (2018/06/08)
A series of Cu4I4 clusters (1-5) supported by two pyrazolate-type zwitterionic ligands N-methyl-[4-(5-R-pyrazolyl)]pyridinium (1: R = tert-butyl; 2: R = trifluoromethyl; 3, 4, 5: R = phenyl) have been prepared and fully characterized
Light-emitting organic metal silver compound with binary emission as well as preparation and application thereof
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Paragraph 0029; 0058-0060, (2018/12/14)
The invention relates to a series of silver halogen series compounds with a one-dimensional chain-shaped structure. A chemical formula is [Ag2LX2]n or [Ag2X2L]n, wherein n is a non-zero natural number; X is selected from halogen atoms including Cl, Br, I
Synthesis and anti-microbial activities of 1,3,5-trisubstituted-pyrazole derivatives containing a pyridyl moiety
Wang, Dun-Jia,Liu, Hua,Kang, Yan-Fang,Hu, Yan-Jun,Wei, Xian-Hong
, p. 2857 - 2860 (2015/06/02)
Claisen condensation of ethyl isonicotinate with different acetophenones gave the corresponding pyridyl-β-diketones, while the treatment with hydrazine hydrate yielded 3,5-disubstituted-1H-pyrazoles, which then converted 1,3,5-trisubstituted-pyrazole deri
Interaction of copper(II) with ditopic pyridyl-β-diketone ligands: Dimeric, framework, and metallogel structures
Dudek, Melanie,Clegg, Jack K.,Glasson, Christopher R. K.,Kelly, Norman,Glou, Kerstin,Gloe, Karsten,Kelling, Alexandra,Buschmann, Hans-Juergen,Jolliffe, Katrina A.,Lindoy, Leonard F.,Meehan, George V.
experimental part, p. 1697 - 1704 (2012/04/11)
The interaction of Cu(II) with three β-diketone ligands of type R 1C(O)CH2C(O)R2 (where R1 = 2-, 3-, or 4-pyridyl and R2 = C6H5, respectively), HL1-HL3, alo
