63128-70-1Relevant academic research and scientific papers
Facile electrosynthesis of π-extended porphyrins
Fang, Yuanyuan,Koszelewski, Dominik,Kadish, Karl M.,Gryko, Daniel T.
supporting information, p. 8864 - 8867 (2014/08/05)
The facile electrosynthesis of π-extended porphyrins is demonstrated for a series of Zn(ii), In(iii), Ir(iii) and free-base meso-substituted derivatives containing the 4,7-dimethoxynaphthalen-1-yl substituent. Electrochemical data suggest that the overall process initially involves two stepwise one-electron oxidations, followed by an intramolecular oxidative aromatic coupling to give the electrooxidized π-extended porphyrin. This journal is the Partner Organisations 2014.
The thermodynamic characteristics of step complex formation in the (5,10,15,20-tetraphenylporphyrinato)(chloro)indium(III)-pyridine-toluene system
Lomova,Malov,Klyuev
, p. 913 - 920 (2009/08/14)
The thermodynamic characteristics, step mechanism, and spectral manifestations of step reactions between (5,10,15,20-tetraphenylporphyrinato) (chloro)indium(III) ((Cl)InTPP) and organic base pyridine (Py) in inert toluene were studied using spectrophotome
The thermodynamic characteristics of sublimation of aluminum and indium complexes with tetraphenylporphin according to the high-temperature mass spectrometry data
Stuzhina,Lomova,Pelipets,Girichev
, p. 154 - 158 (2008/09/18)
The thermodynamic characteristics of vaporization of meso- tetraphenylporphin complexes (X)MTPP (M = Al, In; X = Cl, OH; TPP is the meso-tetraphenylporphin H2TPP dianion) were studied by the Knudsen effusion method with mass spectrometric contr
Photoinduced Cleavage of the Carbon-Indium Bond in Ethylindium(III) Tetraphenylporphyrin
Hoshino, Mikio,Ida, Hiroyuki,Yasufuku, Katsutoshi,Tanaka, Kazunori
, p. 3984 - 3987 (2007/10/02)
The photochemistry of ethylindium(III) tetraphenylporphyrin, C2H5In(III)TPP, in benzene solutions was studied by steady light and laser flash photolysis.From the analysis of the products, the C2H5-In bond in C2H5In(III)TPP was confirmed to be photodissociated.The quantum yields for the photodecomposition of C2H5In(III)TPP were found to be diminished by the addition of ferrocene.However, 2,4,7-trinitro-9-fluorenone, a strong electron acceptor, was found to increase the quantum yields.The laser photolysis studies revealed that the photoreaction of C2H5In(III)TPP occurs via the triplet state originating from the porphyrin ligand.
