63229-33-4Relevant academic research and scientific papers
Process for producing substituted-1-acetyl-3,3-dimethylcyclohexane
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, (2008/06/13)
Described is a process for preparing a genus of substituted 1-acetyl-3,3-dimethylcyclohexanes having the structure: STR1 wherein R1 or one or both of R2 and/or R3 is allyl or methallyl and the other of R1 or R2 and/or R3 is hydrogen, a process for preparing same by means of reacting an allyl or a methallyl halide with acetyl-3,3-dimethyl-cyclohexane using a base according to the reaction: STR2 wherein R is allyl or methallyl and wherein X is chloro or bromo. When such 1-acetyl-3,3-dimethylcyclohexane derivatives are added to consumable materials: (i) In foodstuffs and medicinal products, pineapple, allyl caproate-like, galbanum, woody, fatty, sweet, fruity, citrus, green and vegetable-like aromas and rosey, ionone, Oriental-like, woody, fatty, sweet, fruity, citrus, vegetable-like and waxy flavor characteristics are augmented or enhanced; (ii) In perfumes and perfumed articles, sweet, earthy, animal, green, herbaceous, melony and fruity aromas with pineapple, ambery, galbanum-like, ginger-like and citrusy nuances and tobacco/animal notes are imparted, augmented and/or enhanced; and (iii) In tobaccos and tobacco flavors, green, sweet, fruity, floral and Virginia tobacco-like flavor and aroma nuances are augmented and/or enhanced in the main stream and in the side stream on smoking and, in addition, prior to smoking.
1-Acetyl-3,3-dimethyl-(2-propenyl)cyclohexane
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, (2008/06/13)
Described is the compound 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane, a process for preparing same by means of reacting an allylic halide with acetyl-3,3-dimethylcyclohexane using a phase transfer agent and in a two phase system according to the reaction: STR1 wherein X is chloro or bromo, processes for adding 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane to consumable materials whereby: I. In foodstuffs and medicinal products, fruity, pineapple, allyl-caproate-like, galbanum and woody aroma characteristics are augmented or enhanced and rosey, ionone, oriental-like and woody flavor characteristics are augmented or enhanced; and Ii. In perfumes and perfumed articles, sweet, earthy, animal aromas with pineapple and ambery nuances and tobacco/animal notes are imparted, augmented and/or enhanced And flavor compositions and perfume compositions containing 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane.
