63322-25-8Relevant academic research and scientific papers
An Unusual Stereochemical Directing Effect of Propargylic Oxygen Substituents on an Intramolecular Diels-Alder Reaction
Trost, Barry M.,Holcomb, Ryan C.
, p. 7157 - 7160 (2007/10/02)
Varying the substituent on the oxygen of a propargylic alcohol affects the stereochemical course of an intramolecular Diels-Alder reaction of a diene-yne.
Phosphinyl-Substituted Dienophiles: Their Synthesis and Directive Effects
Darling, Stephen D.,Brandes, Stephanie J.
, p. 1413 - 1416 (2007/10/02)
The unilateral directive influence of the carbonyl group in the Diels-Alder reaction can be negated by a diphenylphosphinyl group.The dienophile 4-(diphenylphosphinyl)-3-buten-2-one (4) was synthesized.Products isolated as a result of the addition of 4 to
