63331-67-9Relevant articles and documents
Technology for synthesizing N-substituted pyrazol-4-borate
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Paragraph 0016; 0017, (2016/12/01)
The invention discloses a technology for synthesizing N-substituted pyrazol-4-borate. The technology comprises the following steps: taking 2-bromomalonaldehyde as a raw material; firstly, causing the 2-bromomalonaldehyde and triethyl orthoformate to react to obtain acetal; transforming bromine into bi(diisopropylamine)boron; then, carrying out a condensation reaction on the bi(diisopropylamine)boron and substituted hydrazine; and finally, causing an obtained product to react with different glycols to obtain the N-substituted pyrazol-4-borate. The method has the advantage of easy obtaining of raw materials, simple synthesis steps and high reaction yield and is suitable for industrialization amplification production.
AN EFFICIENT SYNTHESIS OF α-BROMOACETALS VIA A COMBINED CHEMICAL AND ELECTROCHEMICAL BROMINATION
Aben, R.W.M.,Hanneman, E.J.M.,Scheeren, J.W.
, p. 821 - 826 (2007/10/02)
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