634164-29-7Relevant articles and documents
Hydropyridylation of Olefins by Intramolecular Minisci Reaction
Bordi, Samuele,Starr, Jeremy T.
, p. 2290 - 2293 (2017/05/12)
An unprecedented cheap, mild and easy methodology for an intramolecular Minisci reaction based on a hydrogen atom transfer (HAT) initiated hydrofunctionalization of olefins was developed. The method is suitable for the construction of unusual dihydropyrano-pyridine and 1,2,3,4-tetrahydronaphthiridine structures and, unlike most similar reactions, does not require exclusion of air from the reaction medium.
Diastereoselective intramolecular SmI2-H2O-amine mediated couplings
Dahlen, Anders,Petersson, Annika,Hilmersson, Goeran
, p. 2423 - 2426 (2007/10/03)
The effectiveness of SmI2-H2O-amine mixture for intramolecular couplings was discussed. Diastereoselectivities in the coupling of O-cyclohexanyliodophenol derivatives were provided into heterocycles. The amount of coupled product improved significantly as SmI2, the substrate and amine were premixed followed by a gradual addition of water.