63440-94-8Relevant academic research and scientific papers
Preparation method of cyclic poly (butylene terephthalate) (by machine translation)
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, (2020/06/02)
The invention discloses a cyclic trimetric polybutylene terephthalate preparation method. The method comprises the steps: (a) preparing bis(4-(4-allyl terephthaloyl oxy)butyl)polyethylene terephthalate (III) from bis-(4-hydroxyl butyl)-polyethylene terephthalate (I) and 4-(allyloxy carbonyl)benzoic acid (II) under action of a condensing agent and an auxiliary reagent; (b) preparing cyclic trimetric polybutylene terephthalate precursor (IV) by ring closure of the bis(4-(4-allyl terephthaloyl oxy)butyl)polyethylene terephthalate (III) under the action of a Grubbs catalyst and lewis acid; (c) hydrogenating the cyclic trimetric polybutylene terephthalate precursor under the action of Pd/C to obtain cyclic trimetric polybutylene terephthalate (V). The preparation method disclosed by the invention has the advantages that the raw materials are cheap and easy to obtain, a synthesizing route is simple and short, a yield is high, and conditions are easy to control.(The formula is shown in the description.).
Preparation method and separation method of low polymerization cyclic polymer
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Paragraph 0187-0189; 0236-0278, (2019/11/20)
The invention provides a preparation method of a low polymerization cyclic polymer, and the method comprises the following steps: (1-1) in an organic solvent A, terephthaloyl chloride and 1,4-butanediol undergo esterification reaction under the action of
A practical synthesis of the cyclic butylene terephthalate trimer
Li, Xiaolin,Zhou, Pu,Wu, Wenxuan,Zhan, Li,Liu, Ting,Yang, Fan,Tang, Jie,Yu, Shanbao,Li, Hui,Luo, Yu
, p. 483 - 490 (2018/03/27)
This paper described a practical synthetic approach for the cyclic butylene terephthalate trimer (7). The key step was a ring-closing metathesis, using Grubbs' second-generation catalyst to form the macrocyclic ring. The advantages of this procedure included short reaction steps, simple operations and good yields.
Preparation method of cyclic polyester oligomer
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Paragraph 0044; 0045; 0048; 0049; 0052; 0053, (2017/02/28)
The invention relates to a preparation method of cyclic polyester oligomer and belongs to the technical field of organic synthesis. According to the preparation method, a terephthalic acid derivative and a dihydric alcohol are adopted as raw materials. The raw materials are subjected to condensation reaction through the liquid-liquid interface phase transfer process, and then the cyclic polyester oligomer can be obtained. Compared with the conventional depolymerization cyclization method, the terephthalic acid derivative and the dihydric alcohol are adopted as raw materials. In the presence of a catalyst, a target product is synthesized through controlling the dropping speed. Therefore, the synthetic method is simple and easy to operate, and has a very high industrial application value.
Polybutylene terephthalate cyclic trimerization preparation of (by machine translation)
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, (2018/01/19)
The invention specifically has described a kind of new cyclic trimeric butylene terephthalate (Cyclic PBT Dimer) method for preparing, in the terephthalic chloride and 1, the 4 the protecting [...] butanediol as raw material with oriented synthesis strategy of deprotection of the polybutylene terephthalate cyclic trimerization, in the plastics can be used for the PBT polybutylene terephthalate cyclic trimerization contrast analysis of the impurity with the detection. Said product of this invention the chemical structural formula is: (by machine translation)
