634878-89-0Relevant articles and documents
Synthesis of (±)-Lasubine II Using N-Methoxyamines
Yokoyama, Takashi,Fukami, Yutaro,Sato, Takaaki,Chida, Noritaka
, p. 470 - 473 (2016/03/08)
The synthesis of (±)-lasubine II has been achieved through a three-component allylation capitalizing on the unique properties of N-methoxyamines. This reaction enabled the installation of all the carbon atoms of lasubineII in a single operation. The N-met
A New and Practical Procedure for the Bruylants Reaction. Zinc-Mediated Synthesis of Tertiary Homoallylamines and β-Aminoesters
Bernardi, Luca,Bonini, Bianca F.,Capitò, Elena,Dessole, Gabriella,Fochi, Mariafrancesca,Comes-Franchini, Mauro,Ricci, Alfredo
, p. 1778 - 1782 (2007/10/03)
N,N-Disubstituted α-aminonitriles undergo Bruylants reaction under Barbier and Reformatsky conditions with activated halides, in the presence of zinc and 10 mol% HOAc. The high yields and the simple operational conditions make this reaction an appealing, approach to N,N-disubstituted homoallylamines and β-aminoesters.