63513-01-9Relevant academic research and scientific papers
Activation of silanes by Grubbs' carbene complex Cl2(PCy3)2Ru=CHPh: Dehydrogenative condensation of alcohols and hydrosilylation of carbonyls
Maifeld, Sarah V,Miller, Reagan L,Lee, Daesung
, p. 6363 - 6366 (2002)
This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs' catalyst Cl2(PCy3)2Ru=CHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative conde
Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles
Tan, Meixuan,Zhang, Yugen,Ying, Jackie Y.
experimental part, p. 1390 - 1394 (2009/12/22)
N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC
HYDROSILYLATION
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Page/Page column 14-16, (2008/06/13)
The present invention relates to a process for converting a substrate to a product comprising exposing the substrate to a hydrosilane in the presence of a carbene catalyst.
Hydrosilylation of alkynes catalyzed by ruthenium carbene complexes
Maifeld, Sarah V.,Tran, Michael N.,Lee, Daesung
, p. 105 - 108 (2007/10/03)
Hydrosilylation of terminal alkynes with a variety of silanes catalyzed by Cl2(PCy3)2RuCHPh (1) affords mainly the Z-isomer via trans addition in excellent yields. The presence of a hydroxyl group in close proximity to the
