63521-79-9Relevant academic research and scientific papers
ω-Ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation
Giacomina, Francesca,Riat, David,Alexakis, Alexandre
supporting information; experimental part, p. 1156 - 1159 (2010/05/18)
"Chemical Equation Presented" A new strategy to access highly enantioenriched cyclic compounds (up to 98%) Is proposed using ω-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.
