63521-73-3

Upstream product

• 101100-39-4 1-methyl-2-phenethyl-cyclohexane-1,2-diol 
• 22691-01-6 2-Acetoxy-5-hexene 
• 100-42-5 styrene 
• 197094-57-8 2-Hydroxy-2-phenethyl-cyclohexanone 
• 136068-05-8 1-(2-phenylethyl)cyclopropanol 
• 78-94-4 methyl vinyl ketone 

Downstream Products

• 63521-79-9 1-methyl-2-phenethyl-cyclohexene 

Relevant academic research and scientific papers

Oxidative Cleavage of vic-Diols Using Copper(II) Bromide-Lithium t-Butoxide: A New Route to Unsymmetrical 1,5- and 1,6-Diketones

Unsymmetrical 1,6-diketones were obtained by the copper(II) bromide-lithium t-butoxide oxidation of 1,2-disubstituted 1,2-cyclohexanediols. The diols were easily prepared by the addition of Grignard reagents to 2-trimethylsiloxy-2-cyelohexenone followed by the hydrolysis and treatment of the resulting 2-hydroxycyclohexanones with the second Grignard reagents. Similarly, 1,5-Diketones were obtained using 2-trimethylsiloxy-2-cyclopentenone as a starting material.

Generation of β-Carbonyl Radicals from Cyclopropanol Derivatives by the Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Electron-Rich and -Deficient Olefins

Various β-carbonyl radicals are generated oxidatively from cyclopropanol derivatives by the use of manganese(III) 2-pyridinecarboxylate (Mn(pic)3).These β-carbonyl radicals react with electron-rich olefins such as conjugated silyl enol ethers, a ketene th