63566-54-1Relevant academic research and scientific papers
One-pot synthesis of 2-substituted 3-thioxo-2,3-dihydro-1h-isoindol-1-ones by the reaction of N-substituted 2,N-dilithiobenzamides with isothiocyanates
Kobayashi, Kazuhiro,Fujiwara, Daiki
, p. 1759 - 1765 (2017/09/20)
This paper describes an efficient one-pot method for the preparation of 2-substituted 3-thioxo-1H-isoindol-1-ones (3-thioxoisoindolinones) by the reaction of N-substituted 2,N-dilithiobenzamides, generated by treating N-substituted benzamides with two equ
Investigation of the thionation reaction of cyclic imides
Orzeszko,Maurin,Melon-Ksyta
, p. 1035 - 1040 (2007/10/03)
A series of monothioimides and dithioimides were synthesised using Lawesson's reagent. It has been found that two main effects affect thionation reaction. The high polarity of carbonyl groups leads to good yields of mono- and dithioimides. On the other hand, steric hindrance in the vicinity of the carbonyl group strongly inhibits the replacement of the oxygen atom by sulfur.
