63603-31-6

Basic information

• Product Name: Benzene, [(2-methoxyoctyl)seleno]-
• CAS NO: 63603-31-6
• Molecular Formula: C15H24OSe
• Molecular Weight: 299.315
• Mol File: 63603-31-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-methoxyoctyl)seleno]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-methoxyoctyl)seleno]-(63603-31-6)
• EPA Substance Registry System: Benzene, [(2-methoxyoctyl)seleno]-(63603-31-6)

Safety Data

• Hazardous Substances Data: 63603-31-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 2179-79-5 phenyl selenocyanate 
• 111-66-0 oct-1-ene 
• 1666-13-3 diphenyl diselenide 
• 71766-38-6 Dodecyl phenyl selenoxide 
• 65275-53-8 β-Phenethyl-phenyl-selenoxid 
• 65275-52-7 Isobutyl(phenyl)selenoxid 
• 65275-51-6 n-propyl phenyl selenoxide 
• 34837-55-3 Phenylselenyl bromide 
• 5707-04-0 Phenylselenyl chloride 
• 915127-49-0 N-phenylselenosaccharin 
• 5818-99-5 benzeneselenenic acid 
• 67545-97-5 n-octyl phenyl selenoxide 

Relevant articles and documents

Automated Electrochemical Selenenylations

Integrated electrochemical reactors in automated flow systems were utilised for selenenylation reactions. The automation allowed multiple electrochemical reactions of a programmed sequence to be performed in a fully autonomous way. Many functionalised selenenylated products were synthesised in short reaction times in good to high yields.

A novel role of zeolite NaY in the thermal reaction of alkyl aryl selenoxides in its supercages

Thermal reaction of alkyl aryl selenoxides in the presence of water or methanol in the supercage of zeolite NaY gave β-hydroxy- or β-methoxyalkyl aryl selenides, respectively, and NaY played a novel role to stabilize reactive ArSeOH and to separate an anion of -OH from a carbonium ion which was simultaneously present with the -OH in a supercage.

Novel Method for Electrophilic Selenenylation Using Diselenide with Nitrobenzenesulfonyl Peroxide

Diphenyl diselenide could be readily converted into cationic selenenylating reagent by treating with m-nitrobenzenesulfonyl peroxide, and the intermediate was reacted with olefins in the presence of methanol, phenol, or electorn-rich benzenes in one pot to afford methoxy-, phenoxy-, or arylselenenylated compounds, respectively.