63615-83-8Relevant academic research and scientific papers
VIC-IODOTHIOCYANATES AND IODOISOTHIOCYANATES. PART 6. THE SYNTHESIS OF THIIRANS
Cambie, Richard C.,Rutledge, Peter S.,Strange, Gary A.,Woodgate, Paul D.
, p. 1501 - 1510 (2007/10/02)
Treatment of the vic-iodothiocyanate of either cyclic or acyclic alkenes with lithium triethylborohydride ("Super Hydride") gives thiirans in high yields.The structure of the product from r-1-iodo-1-thiacyanatomethyl-c-4-t-butylcyclohexane has been confirmed by an independent synthesis.
vic-Iodothiocyanates and Iodoisothiocyanates. Part 5. Reactions of Iodoisothiocyanates with Sulphur Nucleophiles
Cambie, Richard C.,Mayer, Gregory D.,Rutledge, Peter S.,Woodgate, Paul D.
, p. 52 - 57 (2007/10/02)
The reactions of vic-iodoisothiocyanates with some sulphur nucleophiles to form either 2-sulphur-substituted 2-thiazolines or thiazolidine-2-thiones are reported.The thiazolidine-2-thione (10) is an effective sulphur-transfer agent for the conversion of oxirans into the corresponding thiirans.
