637036-90-9Relevant academic research and scientific papers
Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR
Johnston, Craig P.,West, Thomas H.,Dooley, Ruth E.,Reid, Marc,Jones, Ariana B.,King, Edward J.,Leach, Andrew G.,Lloyd-Jones, Guy C.
, p. 11112 - 11124 (2018)
The mechanism of CF3 transfer from R3SiCF3 (R = Me, Et, iPr) to ketones and aldehydes, initiated by M+X- (0.004 to 10 mol %), has been investigated by analysis of kinetics (variable-ratio stopped-flo
One-pot synthesis of α-trifluoromethylstyrenes from aryl ketones and the Ruppert–Prakash reagent
Dilman, Alexander D.,Levin, Vitalij V.
, p. 684 - 685 (2021/11/26)
A new synthesis of α-trifluoromethylstyrenes from aromatic ketones and (trifluoromethyl) trimethylsilane is described. The reaction involves nucleophilic trifluoromethylation and elimination of trimethylsilanol, which are performed within one reaction fla
Fe-catalyzed nucleophilic activation of c-si versus allylic C-O bonds: Catalytic trifluoromethylation of carbonyl groups versus tandem trifluormethylation-allylation of olefins
Klein, Johannes E. M. N.,Rommel, Susanne,Plietker, Bernd
supporting information, p. 5802 - 5810 (2015/01/16)
The nucleophilic ferrate salt Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is able to catalyze the direct trifluoromethylation of aldehydes and ketones using Me3SiCF3 as a trifluoromethylating agent. Interception of the C-Si I-b
Efficient synthesis of [18F]trifluoromethane and its application in the synthesis of PET tracers
Van Der Born, Dion,Herscheid,Orru, Romano V.A.,Vugts, Danielle J.
supporting information, p. 4018 - 4020 (2013/07/26)
A new strategy towards [18F]trifluoromethyl-containing compounds is developed. [18F]trifluoromethane is synthesised in a fast and efficient manner and subsequently used in the reaction with aldehydes and ketones forming [18/sup
